147834
Michler′s ketone
98%
Synonym(s):
4,4′-Bis(dimethylamino)benzophenone
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About This Item
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Quality Level
Assay
98%
form
powder
mp
174-176 °C (lit.)
SMILES string
CN(C)c1ccc(cc1)C(=O)c2ccc(cc2)N(C)C
InChI
1S/C17H20N2O/c1-18(2)15-9-5-13(6-10-15)17(20)14-7-11-16(12-8-14)19(3)4/h5-12H,1-4H3
InChI key
VVBLNCFGVYUYGU-UHFFFAOYSA-N
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General description
Michler′s ketone (MK) is a derivative of benzophenone that shows temperature dependent phosphorescence. It also exhibits triplet-triplet absorption spectra at a lower temperature.
Application
MK can be used as an additive that acts as a photoinitiator in the preparation of dyes. It can also be used as a precursor material in the synthesis of 4,4′-bis{N,N,dimethyl, N (2-ethoxy carbonyl-1-propenyl) ammonium hexafluoro antimonate}benzophenone (MKEA).
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 1B - Eye Dam. 1 - Muta. 2
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Michler's ketone.
Report on carcinogens : carcinogen profiles, 12, 270-271 (2011-08-24)
New Push-Pull Dyes Derived from Michler?s Ketone For Polymerization Reactions Upon Visible Lights.
Macromolecules, 46(10), 3761-3770 (2013)
Excited state dynamics of Michler's ketone: a laser flash photolysis study
Research on Chemical Intermediates, 27(1-2), 125-136 (2001)
The journal of physical chemistry. A, 110(14), 4937-4941 (2006-04-08)
Michler's ketone (MK) and tetracyanoethene (TCNE) may be used as a UV-vis probe to investigate the solvent properties of ionic liquids (ILs). In molecular solvents, MK and TCNE give an electron donor-acceptor (EDA) complex, a zwitterionic species or a radical
Journal of chromatographic science, 18(5), 224-232 (1980-05-01)
Sensitive and specific procedures are described for the analysis of residues of gentian violet in animal feed, human urine, and wastewater at levels of 1000 ppm down to 10 ppb, 1 ppb, and 10 ppb, respectively. The cleaned-up extracts were
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