10896
Vinyl laurate
produced by Wacker Chemie AG, Burghausen, Germany, ≥98% (GC)
Synonym(s):
VL
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About This Item
Linear Formula:
CH3(CH2)10COOCH=CH2
CAS Number:
Molecular Weight:
226.36
Beilstein:
1778369
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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grade
produced by Wacker Chemie AG, Burghausen, Germany
Assay
≥98% (GC)
bp
254 °C/1013 hPa (lit.)
solubility
H2O: slightly soluble 1 g/L at 20 °C
density
0.871 g/mL at 20 °C (lit.)
functional group
ester
SMILES string
CCCCCCCCCCCC(=O)OC=C
InChI
1S/C14H26O2/c1-3-5-6-7-8-9-10-11-12-13-14(15)16-4-2/h4H,2-3,5-13H2,1H3
InChI key
GLVVKKSPKXTQRB-UHFFFAOYSA-N
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General description
Vinyl laurate is a clear, colorless to light yellow colored liquid. The flash point is 125°C. It forms aqueous colloidal microgel by copolymerization with N-isopropylacrylamide. The enzymatic acylation of Avicel cellulose with vinyl laurate, a solvent free reaction system, was studied.
Application
Vinyl laurate was used in the synthesis of laurate and stearate esters of corn starch. It was used as the acyl donor during synthesis of sucrose laurate esters catalyzed by Bacillus pseudofirmus AL-89 . Vinyl laurate was also used in the preparation of chirally deuterated benzyl chlorides.
Other Notes
prices for bulk quantities on request
Storage Class Code
10 - Combustible liquids
WGK
WGK 1
Flash Point(F)
257.0 °F
Flash Point(C)
125 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Novel gelling behavior of poly (N-isopropylacrylamide-co-vinyl laurate) microgel dispersions.
Benee LS, et al.
Langmuir, 18(16), 6025-6030 (2002)
Synthesis of higher fatty acid starch esters using vinyl laurate and stearate as reactants.
Junistia L, et al.
Starch/Staerke, 60(12), 667-675 (2008)
Synthesis of sucrose laurate using a new alkaline protease.
Pedersen NR, et al.
Tetrahedron Asymmetry, 14(6), 667-673 (2003)
Stavros Gremos et al.
Bioresource technology, 102(2), 1378-1382 (2010-10-05)
Cellulose esters are an important class of functional biopolymers with great interest in the chemical industry. In this work the enzymatic acylation of Avicel cellulose with vinyl propionate, vinyl laurate and vinyl stearate, has been performed successfully in a solvent
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