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934003

Sigma-Aldrich

Methyl (2,2,2-trifluoroethyl) carbonate

greener alternative

≥98%, anhydrous, battery grade

Synonym(s):

Carbonic Acid Methyl 2,2,2-Trifluoroethyl Ester, FEMC

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About This Item

Empirical Formula (Hill Notation):
C4H5F3O3
CAS Number:
Molecular Weight:
158.08
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

grade

battery grade

Quality Level

Assay

≥98%

form

liquid

greener alternative product characteristics

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impurities

≤250 ppm HF
≤300 ppm H2O

bp

57-59 °C/120 mmHg
90 °C (lit.)

density

1.34 g/mL (lit.)

application(s)

battery manufacturing

greener alternative category

General description

Methyl (2,2,2-trifluoroethyl) carbonate (FEMC), ≥99%, battery grade is one kind of fluorinated linear carbonate. It comes with very low water content (≤ 300.0 ppm) and low impurity of HF (≤ 250.0 ppm) which is ideal for battery research
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Application

Battery-grade methyl (2,2,2-trifluoroethyl) carbonate (FEMC) is an effective additive for improving the performance and stability of lithium-ion batteries. Its outstanding thermal and electrochemical stability makes it a reliable option for high-temperature and high-voltage battery applications. FEMC has been shown to improve battery life, enhance energy density, and increase cycling stability. As an electrolyte additive in lithium-ion batteries (LIBs), FEMC plays an important role in forming a stable solid electrolyte interphase (SEI) and effective passivation of the cathode surfaces, resulting in enhanced discharge capacity and cyclability. Even the addition of 5 wt % of FEMC was found to be very effective in forming a stable SEI layer and protecting the surface of the cathode. FEMC′s high performance makes it an attractive choice for battery manufacturers looking to create safe and efficient battery products.

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

100.4 °F

Flash Point(C)

38 °C


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Interfacial Origin of Performance Improvement and Fade for 4.6 V. LiNi0.5Co0.2Mn0.3O2 Battery Cathodes
Lee Yu-Mi, et al.
The Journal of Physical Chemistry C, 118, 10631?10639-10631?10639 (2014)
Building Safe Lithium-Ion Batteries for Electric Vehicles: A Review
Duan J, et al.
Electrochemical Energy Reviews, 3, 1-42 (2020)
Fluorinated Carbonate-Based Electrolyte for High-Voltage Li(Ni0.5Mn0.3Co0.2)O2/Graphite Lithium-Ion Battery
Jinsol Im, et al.
Journal of the Electrochemical Society, 164 (2017)

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