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279641

Sigma-Aldrich

Sodium tetrakis(1-imidazolyl)borate

97%

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About This Item

Empirical Formula (Hill Notation):
C12H12BN8Na
CAS Number:
68146-65-6
Molecular Weight:
302.08
MDL number:
MFCD00012083
UNSPSC Code:
12352100
PubChem Substance ID:
24856899
NACRES:
NA.22
form:
solid
Assay:
97%

Assay

97%

form

solid

SMILES string

[Na+].c1cn(cn1)[B-](n2ccnc2)(n3ccnc3)n4ccnc4

InChI

1S/C12H12BN8.Na/c1-5-18(9-14-1)13(19-6-2-15-10-19,20-7-3-16-11-20)21-8-4-17-12-21;/h1-12H;/q-1;+1

InChI key

OVRFSDYWKKOQMW-UHFFFAOYSA-N

Application

Sodium tetrakis(1-imidazolyl)borate was used in the:
  • synthesis of series of zwitterionic molecules
  • preparation of poly(imidazolyl)borate organotin(IV) complex
  • precipitation of deuterium cations

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBH9589
30996CKV
09531JE
07308TI
00130PU

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The Study of Sodium Tetrakis (1-imidazolyl) borate in the Precipitation of Deuterium Cations.
Hockman DC, et al.
Analytical Letters, 14(9), 719-730 (1981)
Huaping Li et al.
Journal of the American Chemical Society, 131(25), 8903-8912 (2009-05-23)
A series of zwitterionic molecules were synthesized by addition of iodoalkanes to sodium tetrakis(1-imidazolyl)borate (NaBIm(4)). Single substitution at the N3 site leads to compounds designated as C(n)-BIm(4) (n = 1, 6, 12, 16), where the subscript corresponds to the number
Synthesis and characterization of the first poly (imidazolyl) borate organotin (IV) complex exhibiting a polymeric chain structure.
Pellei M, et al.
Inorganic Chemistry Communications, 4(12), 708-711 (2001)

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