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115665

Sigma-Aldrich

2-Bromo-4′-methoxyacetophenone

97%

Synonym(s):

ω-Bromo-4-methoxyacetophenone, 4-Methoxyphenacyl bromide

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About This Item

Linear Formula:
CH3OC6H4COCH2Br
CAS Number:
2632-13-5
Molecular Weight:
229.07
Beilstein:
743112
EC Number:
220-118-8
MDL number:
MFCD00000201
UNSPSC Code:
12352100
PubChem Substance ID:
24847233
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

mp

69-71 °C (lit.)

storage temp.

2-8°C

SMILES string

COc1ccc(cc1)C(=O)CBr

InChI

1S/C9H9BrO2/c1-12-8-4-2-7(3-5-8)9(11)6-10/h2-5H,6H2,1H3

InChI key

XQJAHBHCLXUGEP-UHFFFAOYSA-N

Gene Information

human ... PTPN6(5777)

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Application

2-Bromo-4′-methoxyacetophenone has been used in the synthesis of light-responsive diblock copolymers containing para-methoxyphenacyl photocleavable side groups.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314,H335

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis of diblock copolymers bearing p-methoxyphenacyl side groups.
Polym. Chem., 2(10), 2284-2292 (2011)
Guido J Noguera et al.
European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 78, 190-197 (2015-07-27)
A set of 4-arylthiazolylhydrazones derived from 1-indanones (TZHs) previously synthesized and assayed against Trypanosoma cruzi, the causative agent of Chagas disease, were explored in terms of conformational analysis. We found that TZHs can adopt four minimum energy conformations: cis (A
Daniel I Perez et al.
Journal of medicinal chemistry, 54(12), 4042-4056 (2011-04-20)
Development of kinase-targeted therapies for central nervous system (CNS) diseases is a great challenge. Glycogen synthase kinase 3 (GSK-3) offers a great potential for severe CNS unmet diseases, being one of the inhibitors on clinical trials for different tauopathies. Following

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