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CRM43557

Supelco

1-Naphthylacetamide

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Synonym(s):

1-Naphthaleneacetamide

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About This Item

Linear Formula:
C10H7CH2CONH2
CAS Number:
Molecular Weight:
185.22
Beilstein:
1945547
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

mp

180-183 °C (lit.)

SMILES string

NC(=O)Cc1cccc2ccccc12

InChI

1S/C12H11NO/c13-12(14)8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2,(H2,13,14)

InChI key

XFNJVKMNNVCYEK-UHFFFAOYSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
1-Naphthylacetamide (NAA) is a synthetic plant auxin that functions as a plant growth regulator. It encourages growth and root formation and prohibits pre-mature shedding of fruits and flowers. It is either applied as a foliar spray to fruits and vegetables or as a seed treatment to promote root formation.
1-Naphthylacetamide is approved for use in the European Union as per the Commission Implementing Regulation (EU) No. 786/2011 in accordance with Regulation No. 1107/2009 for placing the plant protection agents in the market. Following Commission Regulation (EC) No 2016/1015, the maximum residue limit (MRL) for 1-naphthylacetamide and 1-naphthylacetic acid in frozen/fresh fruits and tree nuts is set as 0.06 mg/kg.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The 1-Naphthylacetamide CRM may also find the following uses:

  • Development of a multi-residue method for the determination of 24 plant growth regulators in 50 grape samples using a modified QuEChERS method and liquid chromatography-tandem mass spectrometry (LC-MS/MS)
  • Multi-residue determination of 200 pesticides and their metabolites in honeybee samples using liquid and gas chromatography coupled with tandem mass spectrometry
  • Development and validation of a modified QuEChERS-based method to determine 207 pesticide residues in honey samples using liquid and gas chromatography coupled to tandem mass spectrometry
  • Simultaneous determination of 267 pesticides, their metabolites, and polychlorinated biphenyls in low-mass beebread samples using liquid and gas chromatography in combination with tandem mass spectrometry
  • Development of a method based on the use of many isotopically labeled internal standards to compensate for the matrix effects arising in the multi-residue analysis of pesticides in food samples by gas chromatography-tandem mass spectrometry(GC-MS/MS)

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Tomoyuki Tsuchiyama et al.
Journal of chromatography. A, 1524, 233-245 (2017-10-19)
In the multi-residue analysis of pesticides using GC-MS, the quantitative results are adversely affected by a phenomenon known as the matrix effect. Although the use of matrix-matched standards is considered to be one of the most practical solutions to this
W Hackenbruch et al.
Fortschritte der Medizin, 96(42), 2132-2136 (1978-11-09)
The early symptom in hip joint diseases in children is pain. Pain is localized in the groin and thight, but mostly in the knee. Other important signs are limping and reduced internal rotation. If a hip disease is suspected it
Tomasz Kiljanek et al.
Talanta, 235, 122721-122721 (2021-09-15)
Current work presents developed and validated miniaturized method for residue analysis of 261 pesticides and their metabolites as well as 6 congeners of non-dioxin like polychlorinated biphenyls (ndl-PCB) in a very low mass beebread sample. Sample preparation is based on
Reasoned opinion on the review of the existing maximum residue levels (MRLs) for 1 naphthylacetamide and 1 naphthylacetic acid according to Article 12 of Regulation (EC) No 396/2005
European Food Safety Authority
EFSA Journal, 13(8), 4213-4213 (2015)
Chieh-Han Pu et al.
Journal of food and drug analysis, 26(2), 637-648 (2018-03-24)
A multiresidue analytical method was developed for grapes for the following 24 plant growth regulators: 1-naphthylacetamide, 2,3,5-triiodobenzoic acid, 2,4,5-T, 2-naphthoxyacetic acid, 3-indolylacetic acid, 4-(3-indolyl)-butyric acid, 4-chlorophenoxyacetic acid, 4-nitrophenol, 6-benzylaminopurine, N6-isopentenyladenine, butralin, chlormequat chloride, chlorphonim-Cl, cloprop, forchlorfenuron, gibberellic acid 3, gibberellic acid

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