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809357

Sigma-Aldrich

Lithium hexafluorophosphate solution

greener alternative

in ethylene carbonate and dimethyl carbonate, 2.0 M LiPF6 in EC/DMC=50/50(v/v), battery grade

Synonym(s):

2 M LiPF6 [EC/DMC=50/50(v/v)]

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About This Item

Linear Formula:
LiPF6
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

grade

battery grade

Quality Level

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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concentration

(2.0 M LiPF6 in EC/DMC)

impurities

≤15 ppm H2O
≤50 ppm HF

density

1.3634 g/mL

anion traces

chloride (Cl-): ≤1 ppm
sulfate (SO42-): ≤2 ppm

cation traces

Ca: ≤1 ppm
Fe: ≤1 ppm
K: ≤1 ppm
Na: ≤1 ppm
Pb: ≤1 ppm

application(s)

battery manufacturing

greener alternative category

SMILES string

F[P-](F)(F)(F)(F)F.[Li+]

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

InChI key

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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General description

Battery grade: H2O <15 ppm, HF <50 ppm, and APHA <50 ppm.
Lithium hexafluorophosphate solution in ethylene carbonate and dimethyl carbonate is a class of electrolytic solution that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
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Application

The solutions of LiPF6 in alkyl carbonates find applications as electrolytes in lithium ion batteries and the use of high quality battery grade electrolytes having extremely low water (<15 ppm) and hydrogen fluoride (<50 ppm) contents are critical for achieving high electrochemical performance.

Preparation Note

  • Do not use any glass equipment.
  • Please handle under inert and moisture free environment.

Legal Information

Product of MU Ionic Solutions Corp

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT RE 2 Oral

Target Organs

Bone,Teeth, Kidney

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

77.0 °F

Flash Point(C)

25 °C


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Xu G, et al.
Journal of Material Chemistry A, 3, 4092-4092 (2015)
Lamb J, et al.
Journal of the Electrochemical Society, 162, A2131-A2131 (2015)
Electrodes with high power and high capacity for rechargeable lithium batteries
Kang K, et al.
Science, 311(5763), 977-980 (2006)
Towards greener and more sustainable batteries for electrical energy storage
Larcher D and Tarascon J
Nature Chemistry, 7(1), 19-19 (2015)
Challenges for rechargeable Li batteries
Goodenough JB and Kim Y
Chemistry of Materials, 22(3), 587-603 (2009)

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