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668184

Sigma-Aldrich

N-Methylfulleropyrrolidine

99% (HPLC)

Synonym(s):

MFP, MPC60, NMPC60

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About This Item

Empirical Formula (Hill Notation):
C63H7N
CAS Number:
151872-44-5
Molecular Weight:
777.74
UNSPSC Code:
12352103
NACRES:
NA.23

description

functionalized fullerene

Assay

99% (HPLC)

form

solid

General description

N-Methylfulleropyrrolidine is an acceptor molecule with a fullerene core, and a nitrogen free lone pair that is located at the pyrrolidine ring. It can be used as an intermediate in the synthesis of other functionalized fullerenes. It can be also used in the development of opto-electronic devices.
Photoinduced energy and electron transfer between oligothienylenevinylenes and N-methylfulleropyrrolidine (MP-C60) has been studied in details. MP-C60 acts as an electron acceptor.

Application

Soluble functionalized fullerene. Acts as electron acceptor in mixtures or when linked to π-conjugated molecules and polymers. Used as spectroscopic and redox reference for C60-based molecular heterojunctions.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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First determination of C60 and C70 fullerenes and N-methylfulleropyrrolidine C60 on the suspended material of wastewater effluents by liquid chromatography hybrid quadrupole linear ion trap tandem mass spectrometry
Farre M, et al.
Journal of Hydrology, 383(1-2), 44-51 (2010)
Intra-and intermolecular photoinduced energy and electron transfer between oligothienylenevinylenes and N-methylfulleropyrrolidine.
Apperloo J, et al.
The Journal of Physical Chemistry, 106(1), 21-31 (2002)
Liquid chromatography-atmospheric pressure photoionization-Orbitrap analysis of fullerene aggregates on surface soils and river sediments from Santa Catarina (Brazil)
Sanchis J, et al.
The Science of the Total Environment, 505(1-2), 172-179 (2015)
Intra-and intermolecular photoinduced energy and electron transfer between oligothienylenevinylenes and N-methylfulleropyrrolidine
Apperloo JJ, et al.
The Journal of Physical Chemistry A, 106(1), 21-31 (2002)
Susanna Zakaria et al.
Environmental science and pollution research international, 25(1), 562-571 (2017-10-20)
This study forms the first report on analyzing fullerenes in the Austrian environment and cosmetic products available on the Austrian market. We developed, optimized, and validated a novel method for the analysis of C

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