Skip to Content
Merck
All Photos(4)

Documents

482749

Sigma-Aldrich

Trimesic acid

greener alternative

95%

Synonym(s):

BTC, H3BTC, TMA, Benzene-1,3,5-tricarboxylic acid

Sign Into View Organizational & Contract Pricing
All Photos(4)

About This Item

Linear Formula:
C6H3(CO2H)3
CAS Number:
554-95-0
Molecular Weight:
210.14
Beilstein:
2053080
EC Number:
209-077-7
MDL number:
MFCD00002517
UNSPSC Code:
12352100
PubChem Substance ID:
24871843
NACRES:
NA.22

Assay

95%

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

<5% acetic acid

mp

>300 °C (lit.)

greener alternative category

Enabling,

SMILES string

OC(=O)c1cc(cc(c1)C(O)=O)C(O)=O

InChI

1S/C9H6O6/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15/h1-3H,(H,10,11)(H,12,13)(H,14,15)

InChI key

QMKYBPDZANOJGF-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Trimesic acid (TMA), also known as 1,3,5-benzenetricarboxylic acid, has a self-organized 2D molecular network structure formed by intermolecular hydrogen bonds between the carboxylic acid residues in bulk crystals.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Selected Applications of MOFs in Sustainable Energy Technologies
TMA can be used in the synthesis of metal-organic frameworks (MOFs), which can be used as organic linkers potentially utilized in sensors.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Solid-state self-assembly of a complex from 1, 3, 5-benzenetricarboxylic acid and 1, 3, 5-trihydroxybenzene: influence of strong O-H--O and C-H--O hydrogen bonds
Liu R, et al.
New. J. Chem., 25(7), 890-892 (2001)
A two-dimensional molecular network structure of trimesic acid prepared by adsorption-induced self-organization
Ishikawa Y, et al.
Chemical Communications (Cambridge, England), 3(22), 2652-2653 (2002)
Benign preparation of metal-organic frameworks of trimesic acid and Cu, Co or Ni for potential sensor applications
Sel K, et al.
Journal of Electronic Materials, 44(1), 136-143 (2015)
Hai-Long Jiang et al.
Inorganic chemistry, 49(21), 10001-10006 (2010-10-12)
A series of microporous lanthanide-organic framework enantiomers, Ln(BTC)(H(2)O)·(DMF)(1.1) (Ln = Y 1a, 1b; Tb 2a, 2b; Dy 3a, 3b; Er 4a, 4b; Yb 5a, 5b, BTC = 1,3,5-benzenetricarboxylate; DMF = N,N-dimethylformamide) with unprecedented (6,6)-connected topology have been prepared and characterized.
Leslie J Murray et al.
Journal of the American Chemical Society, 132(23), 7856-7857 (2010-05-21)
Reaction of Cr(CO)(6) with trimesic acid in DMF affords the metal-organic framework Cr(3)(BTC)(2).nDMF (BTC(3-) = 1,3,5-benzenetricarboxylate), which is isostructural to Cu(3)(BTC)(2).3H(2)O. Exchanging DMF for methanol and heating at 160 degrees C under dynamic vacuum for 48 h results in the
View All Related Papers

Articles

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service