418293

Sodium thiophenolate

technical grade, 90%

• Synonym(s): Benzenethiol sodium salt, Sodium thiophenoxide, Thiophenol sodium salt
• Linear Formula: C₆H₅SNa
• CAS Number: 930-69-8
• Molecular Weight: 132.16
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 24866217
• EC Number: 213-224-0
• Beilstein/REAXYS Number: 3597302
• MDL number: MFCD00066460
• Assay: 90%
• Form: powder

Properties

• grade: technical grade
• Quality Segment: 200
• assay: 90%
• form: powder
• mp: >300 °C (lit.)
• SMILES string: [Na]Sc1ccccc1
• InChI: 1S/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
• InChI key: RZWQDAUIUBVCDD-UHFFFAOYSA-M

Description

General description

Sodium thiophenolate can be prepared from the reaction of sodium and thiophenol in diethyl ether.

Application

Sodium thiophenolate has been used for the synthesis of MCoTI-I and MCoTI-II cyclotides, which are naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors. It may be employed in the following studies:

• As probe for the immunoassay and for the detection of label-free protein by surface-enhanced Raman scattering (SERS).
• Preparation of new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (C--N--N)Pt(II) thiophenolate complexes.
• Synthesis of 1,3,5,7,9-pentakis(4-methoxyphenylthio)corannulene, 1,3,5,7,9-pentakis(2-naphthylthio)corannulene and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene.
• Synthesis of Et₄N⁺ salts of homoleptic arylthiolate Ti(IV) complex, [Ti(SPh)₆]^2-.

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges