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Sigma-Aldrich

Cobalt(II) chloride

AnhydroBeads™, −10 mesh, 99.995% trace metals basis

Synonym(s):

Cobalt dichloride, Cobalt muriate, Cobaltous chloride, Dichlorocobalt

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About This Item

Linear Formula:
CoCl2
CAS Number:
7646-79-9
Molecular Weight:
129.84
EC Number:
231-589-4
MDL number:
MFCD00010938
UNSPSC Code:
12352302
PubChem Substance ID:
24865637
NACRES:
NA.23

vapor pressure

40 mmHg ( 0 °C)

product line

AnhydroBeads™

Assay

99.995% trace metals basis

form

beads

impurities

≤15.0 ppm Trace Metal Analysis

particle size

−10 mesh

mp

724 °C (lit.)

SMILES string

Cl[Co]Cl

InChI

1S/2ClH.Co/h2*1H;/q;;+2/p-2

InChI key

GVPFVAHMJGGAJG-UHFFFAOYSA-L

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Application

Precursor for rive-coordinate, heteroleptic thoilate/N complexes which are petential models for cysteine-ligated metalloenzyme activity.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

accessory

Product No.
Description
Pricing

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Shoner, S.C. et al.
Inorganic Chemistry, 37, 5721-5721 (1998)
Cobalt (II) chloride catalyzed acylation of alcohols with acetic anhydride: scope and mechanism.
Iqbal J and Srivastava RR.
The Journal of Organic Chemistry, 57(7), 2001-2007 (1997)
Cobalt (II) chloride catalysed coupling of thiols and anhydrides: a new and efficient synthesis of thiol esters.
Ahmad S and Iqbal J.
Tetrahedron Letters, 27(32), 3791-3794 (1986)
An unusual chemoselectivity in cobalt (II) chloride catalysed cleavage of oxiranes with anilines: A highly regioselective synthesis of β-amino alcohols.
Iqbal J and Pandey A.
Tetrahedron Letters, 31(4), 575-576 (1990)
Ru-Pan Wang et al.
The journal of physical chemistry. C, Nanomaterials and interfaces, 121(45), 24919-24928 (2017-11-25)
We show that with 2p3d resonant inelastic X-ray scattering (RIXS) we can accurately determine the charge-transfer parameters of CoF
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