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Merck

Polymer gel dosimeter based on itaconic acid.

Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine (2015-08-16)
Facundo Mattea, David Chacón, José Vedelago, Mauro Valente, Miriam C Strumia
ABSTRACT

A new polymeric dosimeter based on itaconic acid and N, N'-methylenebisacrylamide was studied. The preparation method, compositions of monomer and crosslinking agent and the presence of oxygen in the dosimetric system were analyzed. The resulting materials were irradiated with an X-ray tube at 158cGy/min, 226cGymin and 298cGy/min with doses up to 1000Gy. The dosimeters presented a linear response in the dose range 75-1000Gy, sensitivities of 0.037 1/Gyat 298cGy/min and an increase in the sensitivity with lower dose rates. One of the most relevant outcomes in this study was obtaining different monomer to crosslinker inclusion in the formed gel for the dosimeters where oxygen was purged during the preparation method. This effect has not been reported in other typical dosimeters and could be attributed to the large differences in the reactivity among these species.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
N,N′-Methylenebis(acrylamide), 99%
Sigma-Aldrich
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N,N′-Methylenebisacrylamide, suitable for electrophoresis (after filtration or allowing insolubles to settle)
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Sodium phosphate monobasic, meets USP testing specifications, anhydrous
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