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Key Documents

D0890

Sigma-Aldrich

1,2:3,5-Di-O-isopropylidene-α-D-apiose

Synonym(s):

α-D-Apiose diacetonide

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About This Item

Empirical Formula (Hill Notation):
C11H18O5
CAS Number:
Molecular Weight:
230.26
MDL number:
UNSPSC Code:
12352201
PubChem Substance ID:

form

solid

storage temp.

−20°C

SMILES string

CC1(C)OCC2(COC3OC(C)(C)OC23)O1

InChI

1S/C11H18O5/c1-9(2)13-6-11(16-9)5-12-8-7(11)14-10(3,4)15-8/h7-8H,5-6H2,1-4H3

InChI key

WGCOBUGUSFKJSL-UHFFFAOYSA-N

Application

Di-O-isopropylidene-α-D-apiose may be used as a reagent for the organic synthesis of conformationally semirigid diacylglycerol (DAG) analogues embedded into five-membered ring lactones.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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J Lee et al.
Journal of medicinal chemistry, 39(25), 4912-4919 (1996-12-06)
In the present investigation, the last two possible modes of generating conformationally semirigid diacylglycerol (DAG) analogues embedded into five-membered ring lactones as templates III and IV are investigated. The first two templates studied in previous investigations corresponded to 2-deoxyribonolactone (template

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