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09659

Sigma-Aldrich

(±)-Boc-α-phosphonoglycine trimethyl ester

≥97.0% (HPLC)

Synonym(s):

(±)-Trimethyl-Boc-α-phosphonoglycinate

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About This Item

Empirical Formula (Hill Notation):
C10H20NO7P
CAS Number:
89524-98-1
Molecular Weight:
297.24
Beilstein:
4296364
MDL number:
MFCD02178893
UNSPSC Code:
12352209
PubChem Substance ID:
329748789
NACRES:
NA.22

Assay

≥97.0% (HPLC)

form

powder or crystals

reaction suitability

reaction type: Boc solid-phase peptide synthesis

color

colorless to white

application(s)

peptide synthesis

SMILES string

COC(=O)C(NC(=O)OC(C)(C)C)P(=O)(OC)OC

InChI

1S/C10H20NO7P/c1-10(2,3)18-9(13)11-7(8(12)15-4)19(14,16-5)17-6/h7H,1-6H3,(H,11,13)

InChI key

LJHAPRKTPAREGO-UHFFFAOYSA-N

Other Notes

Wittig-Horner reagent for preparing (Z)-Boc-protected dehydroamino acid derivatives; and saturated, unnatural amino acids by subsequent asymmetric hydrogenation.

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H301

Precautionary Statements

P301 + P310

Hazard Classifications

Acute Tox. 3 Oral

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCBG8164V
1402506V
1402506
1317086
1130620

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K.B. Jorgensen et al.
Tetrahedron, 55, 10527-10527 (1999)
U. Schmidt et al.
Synthesis, 1025-1025 (1992)
U. Schmidt et al.
Synthesis, 487-487 (1992)

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