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W519103

Sigma-Aldrich

Methyl formate

≥95%

Synonym(s):

Formic acid methyl ester

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About This Item

Linear Formula:
HCO2CH3
CAS Number:
107-31-3
Molecular Weight:
60.05
Beilstein:
1734623
EC Number:
203-481-7
MDL number:
MFCD00003291
UNSPSC Code:
12164502
PubChem Substance ID:
24902082
Flavis number:
9.642
NACRES:
NA.21
Assay:
≥95%
application(s):
flavors and fragrances
bp:
32-34 °C (lit.)
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biological source

synthetic

vapor density

2.1 (vs air)

Assay

≥95%

form

liquid

autoignition temp.

842 °F

expl. lim.

23 %

refractive index

n20/D 1.343 (lit.)

pH

4.0-5.0 (20 °C, 200 g/L)

bp

32-34 °C (lit.)

mp

−100 °C (lit.)

density

0.974 g/mL at 20 °C (lit.)

application(s)

flavors and fragrances

Documentation

see Safety & Documentation for available documents

food allergen

no known allergens

Organoleptic

fruity; plum

SMILES string

[H]C(=O)OC

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

InChI key

TZIHFWKZFHZASV-UHFFFAOYSA-N

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General description

Methyl formate finds application as a fumigant in raisins and dried currants.[1]

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

-2.2 °F - closed cup

Flash Point(C)

-19 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBH1564
STBJ0620
STBG1536V
STBF0859V
MKBP5658V

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Winter R
A Consumer's Dictionary of Food Additives, 352-352 null
John F Marlier et al.
The Journal of organic chemistry, 70(5), 1737-1744 (2005-02-26)
Multiple isotope effects have been measured for the acid-catalyzed hydrolysis of methyl formate in 0.5 M HCl at 20 degrees C. The isotope effects in the present investigation include the carbonyl carbon (13k = 1.028 +/- 0.001), the carbonyl oxygen
D Cain et al.
The Journal of organic chemistry, 66(18), 6092-6095 (2001-09-01)
Free-energy barriers of 9.85 and 11.91 +/- 0.15 kcal/mol at -70.8 degrees C were found by dynamic NMR spectroscopy for the E-to-Z and Z-to-E conversions, respectively, of methyl formate (1) enriched in 13C to 99% for the carbonyl carbon [methyl
T Sethre et al.
International archives of occupational and environmental health, 73(6), 401-409 (2000-09-28)
The aim of the study was to investigate the acute effects of experimental methylformate exposure on the nervous system. In an exposure chamber, 20 subjects were exposed to methylformate at 100 ppm [Swiss maximum allowable concentration (MAC)] for 8 h.
A Nihlén et al.
International archives of occupational and environmental health, 73(7), 479-487 (2000-11-01)
A toxicokinetic (TK) model was developed to describe the inhalation exposure in humans to methyl formate (MF), a catalyst used in foundries, and to discuss biological monitoring. The TK model consisted of four compartments: MF, the metabolites--methanol (MeOH) and formic
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