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778362

Sigma-Aldrich

5-Methyl-5-allyloxycarbonyl-1,3-dioxan-2-one

97%

Synonym(s):

5-Methyl-2-oxo-1,3-dioxane-5-carboxylic acid, 2-propen-1-yl ester, Allyl 5-methyl-2-oxo-1,3-dioxane-5-carboxylate, Allyl functionalized carbonate monomer, MAC

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About This Item

Empirical Formula (Hill Notation):
C9H12O5
CAS Number:
Molecular Weight:
200.19
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Assay

97%

form

solid

mp

65-70 °C

storage temp.

−20°C

SMILES string

O=C1OCC(C(OCC=C)=O)(C)CO1

InChI

1S/C9H12O5/c1-3-4-12-7(10)9(2)5-13-8(11)14-6-9/h3H,1,4-6H2,2H3

InChI key

OPWZLMZGHGAFNG-UHFFFAOYSA-N

Application

This monomer contains a pendant allyl group for thiol-ene click chemistry; to be copolymerized with lactides or glycolides for biodegradable polymers containing pendant functional groups.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Kerry A Hamilton et al.
Water research, 119, 288-303 (2017-05-14)
A quantitative microbial risk assessment (QMRA) of opportunistic pathogens Legionella pneumophila (LP) and Mycobacterium avium complex (MAC) was undertaken for various uses of roof-harvested rainwater (RHRW) reported in Queensland, Australia to identify appropriate usages and guide risk management practices. Risks
Juliet Hounsome et al.
The Cochrane database of systematic reviews, (8), CD011052-CD011052 (2016-08-11)
Accidental awareness during general anaesthesia (AAGA) is when a patient unintentionally becomes conscious during a procedure performed with general anaesthesia and subsequently has explicit recall of this event. Incidence estimates for AAGA vary, with the most common estimate being one
Khursheed N Jeejeebhoy et al.
The American journal of clinical nutrition, 101(5), 956-965 (2015-03-06)
Nutritional assessment commonly includes multiple nutrition indicators (NIs). To promote efficiency, a minimum set is needed for the diagnosis of malnutrition in the acute care setting. The objective was to compare the ability of different NIs to predict outcomes of
Lifang Feng et al.
Nucleic acids research, 45(16), 9481-9502 (2017-09-22)
Developmentally programmed genome rearrangement accompanies differentiation of the silent germline micronucleus into the transcriptionally active somatic macronucleus in the ciliated protozoan Tetrahymena thermophila. Internal eliminated sequences (IES) are excised, followed by rejoining of MAC-destined sequences, while fragmentation occurs at conserved
M Coburn et al.
British journal of anaesthesia, 120(1), 127-137 (2018-02-06)
Postoperative delirium occurs frequently in elderly hip fracture surgery patients and is associated with poorer overall outcomes. Because xenon anaesthesia has neuroprotective properties, we evaluated its effect on the incidence of delirium and other outcomes after hip fracture surgery. This

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