Skip to Content
Merck
All Photos(3)

Documents

516805

Sigma-Aldrich

4,4′-Oxydianiline

97%

Synonym(s):

4,4′-Diaminodiphenyl ether, 4-Aminophenyl ether

Sign Into View Organizational & Contract Pricing
All Photos(3)

About This Item

Linear Formula:
O(C6H4NH2)2
CAS Number:
101-80-4
Molecular Weight:
200.24
Beilstein:
475735
EC Number:
202-977-0
MDL number:
MFCD00007863
UNSPSC Code:
12352100
PubChem Substance ID:
24873898
NACRES:
NA.22

vapor pressure

10 mmHg ( 240 °C)

Assay

97%

form

solid

mp

188-192 °C (lit.)

SMILES string

Nc1ccc(Oc2ccc(N)cc2)cc1

InChI

1S/C12H12N2O/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H,13-14H2

InChI key

HLBLWEWZXPIGSM-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

4,4′-Oxydianiline can be used as a reactant to synthesize:
  • Aromatic polyamides by polycondensation with aromatic dicarboxylic acids.
  • Azomethine bisphenols by reacting with aromatic aldehydes, which can be used to synthesize polyazomethines by the oxidative polycondensation in the presence of NaOCl as an oxidant.
  • Polyguanamines by the chemoselective polycondensation with 2-amino-4,6-dichloro-1,3,5-triazine in the presence of potassium carbonate as a base.
It can also be used for the functionalization of carbon nanotubes, which can react with terminal dianhydrides to synthesize polyimide aerogels.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 1 - Carc. 1B - Muta. 1B - Repr. 2 - Skin Sens. 1 - STOT RE 2 Oral

Target Organs

Thyroid

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

426.2 °F - closed cup

Flash Point(C)

219 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Gas permeability and permselectivity in polyimides based on 3, 3', 4, 4'-biphenyltetracarboxylic dianhydride.
Tanaka K, et al.
Journal of Membrane Science, 47(1), 203-215 (1989)
Synthesis, characterization, optical and electrical properties of thermally stable polyazomethines derived from 4, 4'-oxydianiline.
Dineshkumar S, et al.
Journal of Adhesion Science and Technology, 29(23), 2605-2621 (2015)
Pervaporation of water/acetic acid through polyimide membranes from 3, 3', 4, 4'-benzophenone tetracarboxylic dianhydride and 4, 4'-oxydianiline.
Moon YD, et al.
Polym. Bull., 29(3-4), 431-438 (1992)
Copolyimides from 2, 3, 3', 4'-biphenyltetracarboxylic dianhydride and pyromellitic dianhydride with 4, 4'-oxydianiline.
Hergenrother PM, et al.
Polymer, 45(16), 5441-5449 (2004)
Anders Lennartson et al.
Chirality, 27(7), 425-429 (2015-06-03)
We studied the spontaneous formation of chiral crystals of four diaryl ethers, 3-phenoxybenzaldehyde, 1; 1,3-dimethyl-2-phenoxybenzene, 2; di(4-aminophenyl) ether, 3; and di(p-tolyl) ether, 4. Compounds 1, 3, and 4 form conformationally chiral molecules in the solid state, while the chirality of
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service