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253324

Sigma-Aldrich

3-Carboxy-PROXYL

98%

Synonym(s):

3-(Carboxy)-2,2,5,5-tetramethyl-1-pyrrolidinyloxy, 3-Carboxy-2,2,5,5-tetramethyl-1-pyrrolidinyloxy, free radical

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5.550,00 kr.

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1 G
5.550,00 kr.

About This Item

Empirical Formula (Hill Notation):
C9H16NO3
CAS Number:
Molecular Weight:
186.23
EC Number:
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22
Assay:
98%

5.550,00 kr.


Please contact Customer Service for Availability

Request a Bulk Order

Quality Level

Assay

98%

mp

200 °C (dec.) (lit.)

storage temp.

2-8°C

SMILES string

CC1(C)CC(C(O)=O)C(C)(C)N1[O]

InChI

1S/C9H16NO3/c1-8(2)5-6(7(11)12)9(3,4)10(8)13/h6H,5H2,1-4H3,(H,11,12)

InChI key

GEPIUTWNBHBHIO-UHFFFAOYSA-N

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Application

Spin-label that has been used to study molecular migration and long-term stability of seeds and pollen. Has been covalently attached to oligonucleotides to prepare a DNA probe sensitive to electron spin resonance. The acetoxymethyl ester is an esterase-sensitive probe that crosses the blood-brain barrier for electron spin resonance-computed tomographic imaging.
Spin-label. The anionic form has been used to determine distribution coefficients of neutral solubilizates in anionic micelles.[1]
Used in the preparation of a tetraphenylporphyrin bearing a nitroxyl radical.[2]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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I Seimenis et al.
Magnetic resonance in medicine, 37(4), 552-558 (1997-04-01)
Proton electron double resonance imaging (PEDRI) was used for monitoring in vivo the distribution, metabolism and, in particular, the excretion mechanism of the exogenous nitroxide free radical proxyl carboxylic acid (PCA) in the rat. PCA clearance half-lives through liver, abdominal
J. Chem. Soc., Faraday, 87, 947-947 (1991)
V Quaresima et al.
Physics in medicine and biology, 43(7), 1937-1947 (1998-08-14)
Much outstanding progress concerning the application of ESR spectroscopy/imaging in the biomedical field has been made in recent years. The literature in this field has already been specifically covered by several reviews. The aim of this article is to provide
M A Foster et al.
Physics in medicine and biology, 43(7), 1893-1897 (1998-08-14)
Proton-electron double-resonance imaging (PEDRI) has considerable value for study of the distribution and elimination pathways of nitroxide free radicals (NFRs). This has been illustrated by its use in studies of kidney function in the living rat in which the NFR
Chemistry Letters (Jpn), 33, 460-460 (2004)

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