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242861

Sigma-Aldrich

Chloroiodomethane

97%

Synonym(s):

Chloromethyl iodide, Iodochloromethane

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About This Item

Linear Formula:
ClCH2I
CAS Number:
593-71-5
Molecular Weight:
176.38
Beilstein:
1730802
EC Number:
209-804-8
MDL number:
MFCD00001078
UNSPSC Code:
12352100
PubChem Substance ID:
24854589
NACRES:
NA.22

Assay

97%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.582 (lit.)

bp

108-109 °C (lit.)

density

2.422 g/mL at 25 °C (lit.)

SMILES string

ClCI

InChI

1S/CH2ClI/c2-1-3/h1H2

InChI key

PJGJQVRXEUVAFT-UHFFFAOYSA-N

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General description

The photolysis of chloroiodomethane in cryogenic matrices along with recombination of the nascent radical pair was studied.

accessory

Product No.
Description
Pricing

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H301,H315,H319,H335

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Thomas J Preston et al.
The Journal of chemical physics, 135(11), 114503-114503 (2011-09-29)
Photolysis of chloroiodomethane (CH(2)ClI) in cryogenic matrices followed by recombination of the nascent radical pair produces an isomer (CH(2)Cl-I) that features a halogen-halogen (Cl-I) bond. Using ultrafast laser pulses, it is possible to follow the formation of this isomer by
Andrew J Sumner et al.
Environmental science & technology, 53(14), 8216-8226 (2019-07-06)
A number of flowback samples derived from horizontally drilled hydraulic fracturing (HDHF) operations reveal consistent detections of halogenated organic species , yet the source of these compounds remains uncertain. Studies simulating subsurface conditions have found that oxidative "breakers" can halogenate certain

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