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145831

Sigma-Aldrich

Allylamine

98%

Synonym(s):

2-Propen-1-ylamine, 3-Amino-1-propene

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About This Item

Linear Formula:
CH2=CHCH2NH2
CAS Number:
107-11-9
Molecular Weight:
57.09
Beilstein:
635703
EC Number:
203-463-9
MDL number:
MFCD00008199
UNSPSC Code:
12352100
PubChem Substance ID:
24848749
NACRES:
NA.22
form:
liquid
Assay:
98%
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vapor density

2 (vs air)

vapor pressure

4.09 psi ( 20 °C)

Assay

98%

form

liquid

expl. lim.

22 %

refractive index

n20/D 1.420 (lit.)

bp

53 °C (lit.)

mp

−88 °C (lit.)

solubility

alcohol: miscible
chloroform: miscible
diethyl ether: miscible
water: miscible

density

0.761 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

NCC=C

InChI

1S/C3H7N/c1-2-3-4/h2H,1,3-4H2

InChI key

VVJKKWFAADXIJK-UHFFFAOYSA-N

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Application

Allylamine can be used:
  • To prepare a chemical gradient through plasma co-polymerization of octadiene and allylamine polymer on nanoporous alumina.[1]
  • As a monomer to prepare plasma polymerized allylamine films in the study of their reactivity on Au and Si.[2]
  • In a direct monocarboxymethylation reaction to yield N-formyl glycine derivatives.[3]

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

-4.0 °F - closed cup

Flash Point(C)

-20 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBK5708
STBK3843
STBK3844
STBK1266
STBJ8032

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A new approach to the immobilisation of poly (ethylene oxide) for the reduction of non-specific protein adsorption on conductive substrates.
Cole MA, et al.
Surface Science, 601(7), 1716-1725 (2007)
A mild and efficient method for the one-pot monocarboxymethylation of primary amines
Gibbs Timothy JK, et al.
Synlett, 2007(10), 1573-1576 (2007)
Chemical reactivity of plasma polymerized allylamine (PPAA) thin films on Au and Si: Study of the thickness influence and aging of the films.
Moreau N, et al.
Surface and Coatings Technology, 205, S462-S465 (2011)
Synlett, 1573-1573 (2007)
Versatile gradients of chemistry, bound ligands and nanoparticles on alumina nanopore arrays
Michelmore A, et al.
Nanotechnology, 22(41), 415601-415601 (2011)
View All Related Papers

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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