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259225

Sigma-Aldrich

1,5-Diphenylcarbazide

ACS reagent

Synonym(s):

DPC, 1,5-Diphenylcarbohydrazide, sym.-Diphenylcarbazide

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About This Item

Linear Formula:
C6H5NHNHCONHNHC6H5
CAS Number:
Molecular Weight:
242.28
Beilstein:
752039
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21
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grade

ACS reagent

Quality Level

form

solid

ign. residue

≤0.05%

mp

170-175 °C (lit.)
173-176 °C

solubility

aqueous acetone: passes test

density

1,31  g/cm3

suitability

passes test for sensitivity to chromate

functional group

amine
hydrazide

SMILES string

O=C(NNc1ccccc1)NNc2ccccc2

InChI

1S/C13H14N4O/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14-15H,(H2,16,17,18)

InChI key

KSPIHGBHKVISFI-UHFFFAOYSA-N

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General description

1,5-Diphenylcarbazide is a colorimetric reagent commonly employed in the determination of trace metals.[1]

Application

1,5-Diphenylcarbazide may be used in the following processes:
  • As a reagent for the quantification of palladium and platinum by spectrophotometry.[2]
  • As a mediator for the functionalization of carbon paste electrodes employed in the estimation of Hg(II) ions by differential pulse voltammetry.[3]
  • Fabrication of gold nanoparticles that can be employed for the detection of chromium (VI) ions via colorimetry.[4]

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Customers Also Viewed

Surface-enhanced Raman scattering and DFT investigation of 1, 5-diphenylcarbazide and its metal complexes with Ca (II), Mn (II), Fe (III) and Cu (II).
Szabo L, et al.
Journal of Molecular Structure, 1073, 10-17 (2014)
Photometric and visual detection of Cr (VI) using gold nanoparticles modified with 1, 5-diphenylcarbazide.
Liu, L, et al.
Microchimica Acta, 1-7 (2016)
Spectrophotometric determination of platinum and palladium with 1, 5-diphenylcarbazide
Brajter K, et al.
Fresenius Journal of Analytical Chemistry, 328(1), 598-598 (1987)
Determination of hexavalent chromium by species specific isotope dilution mass spectrometry and ion chromatography-1, 5-diphenylcarbazide spectrophotometry.
Tirez K, et al.
Journal of Analytical Atomic Spectrometry, 18(8), 922-932 (2003)
Oxidation of 1,5-diphenylcarbazide as a measure of photosystem 2 activity in subchloroplast fragments.
L P Vernon et al.
Biochemical and biophysical research communications, 36(6), 878-884 (1969-09-10)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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