D5130
Dithizone
Practical Grade
Synonym(s):
Diphenylthiocarbazone
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About This Item
Linear Formula:
C6H5NHNHCSN=NC6H5
CAS Number:
Molecular Weight:
256.33
Beilstein:
748838
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21
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Quality Level
form
powder
mp
168 °C (dec.) (lit.)
SMILES string
S=C(NNc1ccccc1)\N=N\c2ccccc2
InChI
1S/C13H12N4S/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14H,(H,16,18)/b17-15+
InChI key
UOFGSWVZMUXXIY-BMRADRMJSA-N
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Application
Dithizone may be used for the following purposes:
- As an extracting agent for the extraction of copper in kerosene.
- Alteration of graphene oxide nano-sheet to improve its adsorption capacity.
- Preparation of magnetite nanoparticles/silicon dioxide-dithizone-palladium complex (MNPs/SiO2-DTZ-Pd complex), which is employed as a catalyst for Suzuki type coupling reactions.
- Surface modification of mesoporous silica membranes.
- As a titrant in the quantitative determination of heavy metals.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Dithizone-modified graphene oxide nano-sheet as a sorbent for pre-concentration and determination of cadmium and lead ions in food.
Moghadam Zadeh, HR, et al.
Food Additives & Contaminants. Part A, Chemistry, Analysis, Control, Exposure & Risk Assessment, 32(11), 1851-1857 (2015)
Synthesis, characterization, and application of palladium-dithizone immobilized on magnetic nanoparticles as an efficient and recoverable catalyst for Suzuki type coupling reactions.
Ghorbani-Choghamarani A and Rabiei H.
Tetrahedron Letters, 57(1), 159-162 (2016)
Robust transparent mesoporous silica membranes as matrices for colorimetric sensors.
Kim D and Chmelka BF.
Royal Society of Chemistry Advances, 5(21), 16549-16553 (2015)
G J Lees et al.
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The ability of metal chelating agents to affect seizure-induced neuronal death caused by intra-amygdaloid injections of kainic acid was investigated. N,N,N',N'-tetrakis(2-pyridylmethyl)ethylenediamine (TPEN), diethyldithiocarbamate (DEDTC) and diphenylthiocarbazone (dithizone), administered simultaneously or within 30 min of a kainate injection, all failed to
Effect of various solvents on the absorption spectra of dithizone and DFT calculations.
Rauf MA, et al.
Journal of Molecular Liquids, 211, 332-337 (2015)
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