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45804

Supelco

Triphenylene

analytical standard

Synonym(s):

9,10-Benzophenanthrene

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About This Item

Empirical Formula (Hill Notation):
C18H12
CAS Number:
Molecular Weight:
228.29
Beilstein:
1342908
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

bp

438 °C (lit.)

mp

195-198 °C (lit.)

application(s)

environmental

format

neat

SMILES string

c1ccc2c(c1)c3ccccc3c4ccccc24

InChI

1S/C18H12/c1-2-8-14-13(7-1)15-9-3-4-11-17(15)18-12-6-5-10-16(14)18/h1-12H

InChI key

SLGBZMMZGDRARJ-UHFFFAOYSA-N

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General description

Triphenylene belongs to the class of polycyclic aromatic hydrocarbons, which is commonly employed as a substrate for use as a precursor for the synthesis of graphenes, carbon nanotubes, buckminsterfullerenes as well as polycyclic heteroaromatics.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Triphenylene may be used as an analytical reference standard for the quantification of the analyte in environmental samples using gas chromatography technique.

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Pictograms

CorrosionEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Analysis of polycyclic aromatic hydrocarbons (PAHs) in environmental samples: a critical review of gas chromatographic (GC) methods
Poster.LD, et al.
Analytical and Bioanalytical Chemistry, 386(4), 859-881 (2006)
Analysis of polycyclic aromatic hydrocarbons (PAHs) in environmental samples: a critical review of gas chromatographic (GC) methods
Prasad RP, et al.
Journal of Chemical Sciences (Bangalore), 126(5), 1311-1321 (2014)
Lin Jiang et al.
Organic letters, 13(12), 3020-3023 (2011-05-25)
Triphenylene has been successfully fused to the porphyrin periphery through a convenient oxidative ring-closure reaction. Bistriphenylene-fused porphyrins and a dibenzo[fg,op]tetracene-fused porphyrin have also been obtained using a similar approach. These π-extended porphyrins exhibited broadened and bathochromic shifted UV-vis absorptions.
Fabián Vaca Chávez et al.
The journal of physical chemistry. B, 116(8), 2339-2346 (2012-02-23)
The Larmor frequency and temperature dependence of the proton nuclear magnetic resonance (NMR) spin-lattice relaxation time was measured in the isotropic and columnar phases of both chain-end fluorinated triphenylene disk-like and fully hydrogenated molecules. In the columnar phase, the results
Jeongho Jay Lee et al.
Angewandte Chemie (International ed. in English), 51(34), 8490-8494 (2012-07-24)
Orient and conduct: Triphenylene-based discotic ionic liquid crystals (ILCs) with six imidazolium ion pendants can disperse pristine single-walled carbon nanotubes (SWNTs). When the ILC is columnarly assembled, doping with SWNTs results in macroscopic homeotropic columnar orientation. Combination of shear and

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