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B67201

Sigma-Aldrich

1-Bromo-4-fluorobenzene

99%

Synonym(s):

1-Fluoro-4-bromobenzene, 4-Bromo-1-fluorobenzene, 4-Fluoro-1-bromobenzene, p-Fluorophenyl bromide

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€24.00
100 G
€54.00
500 G
€169.00

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25 G
€24.00
100 G
€54.00
500 G
€169.00

About This Item

Linear Formula:
BrC6H4F
CAS Number:
460-00-4
Molecular Weight:
175.00
Beilstein:
774102
EC Number:
207-300-2
MDL number:
MFCD00000342
UNSPSC Code:
12352100
PubChem Substance ID:
24891932
NACRES:
NA.22

€24.00

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Quality Level

100

Assay

99%

refractive index

n20/D 1.527 (lit.)

bp

150 °C (lit.)

mp

−16 °C (lit.)

density

1.593 g/mL at 25 °C (lit.)

SMILES string

Fc1ccc(Br)cc1

InChI

1S/C6H4BrF/c7-5-1-3-6(8)4-2-5/h1-4H

InChI key

AITNMTXHTIIIBB-UHFFFAOYSA-N

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General description

1-Bromo-4-fluorobenzene is commonly used in the Suzuki-Miyaura coupling reaction to form carbon-carbon bonds.[1]

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

127.4 °F - closed cup

Flash Point(C)

53 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000422462
0000418081
0000418081
0000422462
0000388811

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Suzuki-Miyaura CC coupling reactions catalyzed by supported Pd nanoparticles for the preparation of fluorinated biphenyl derivatives
Erami, R et al.
Catalysts, 7(3), 76-76 (2017)
Qian Luo et al.
Journal of chromatography. A, 1365, 45-53 (2014-09-27)
When iodide and natural organic matter are present in raw water, the formation of iodo-trihalomethanes (Iodo-THMs), haloacetonitriles (HANs), and halonitromethanes (HNMs) pose a potential health risk because they have been reported to be more toxic than their brominated or chlorinated
Michael Phillips et al.
Health physics, 108(5), 538-546 (2015-03-27)
There is widespread interest in the development of tools to estimate radiation exposures. Exhaled breath provides a novel matrix for assessing biomarkers that could be correlated with exposures. The use of exhaled breath for estimating radiation exposure is warranted, as
Jae Kwak et al.
Journal of separation science, 38(14), 2463-2469 (2015-05-07)
Volatile organic compounds were collected and analyzed from a variety of indoor and outdoor air samples to test whether human-derived compounds can be readily detected in the air and if they can be associated with human occupancy or presence. Compounds
Christoph Hutzler et al.
Archives of toxicology, 88(7), 1295-1308 (2014-06-25)
Electronic (e-)cigarettes have emerged in recent years as putative alternative to conventional tobacco cigarettes. These products do not contain typical carcinogens that are present in tobacco smoke, due to the lack of combustion. However, besides nicotine, hazards can also arise

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