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752096

Sigma-Aldrich

Sodium tert-pentoxide solution

40% in toluene

Synonym(s):

tert-Amyl alcohol sodium salt, Sodium tert-amoxide

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100 ML
€78.60
500 ML
€321.00

About This Item

Empirical Formula (Hill Notation):
C5H11NaO
CAS Number:
14593-46-5
Molecular Weight:
110.13
MDL number:
MFCD00064245
UNSPSC Code:
12352001
PubChem Substance ID:
329766260
NACRES:
NA.22

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form

liquid

concentration

40% in toluene

density

0.918 g/mL at 25 °C

SMILES string

[Na+].CCC(C)(C)[O-]

InChI

1S/C5H11O.Na/c1-4-5(2,3)6;/h4H2,1-3H3;/q-1;+1

InChI key

CGRKYEALWSRNJS-UHFFFAOYSA-N

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Related Categories

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2

Target Organs

Central nervous system, Respiratory system

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

39.2 °F

Flash Point(C)

4 °C

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR0051
SHBM6422
SHBL6106
SHBK8605
SHBJ8749

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Brandon K Tate et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(28), 10160-10169 (2015-06-11)
Alkoxide-bridged disilver cations react with dihydrogen to form hydride-bridged cations, releasing free alcohol. Hydrogenolysis of neutral silver fluorides affords hydride-bridged disilver cations as their bifluoride salts. These reactions proceed most efficiently when the supporting ligands are expanded N-heterocyclic carbenes (NHCs)

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