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747785

Sigma-Aldrich

[Ru(bpm)3][Cl]2

Synonym(s):

Dichlorotris(2,2′-bipyrimidine-N1,N1′)ruthenium(II), Tris(2,2′-bipyrimide)ruthenium(II) dichloride

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About This Item

Empirical Formula (Hill Notation):
C24H18Cl2N12Ru
CAS Number:
65034-88-0
Molecular Weight:
646.46
UNSPSC Code:
12161600
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: Photocatalysis

impurities

≤15 wt. % ethylene glycol

mp

>300 °C

SMILES string

C1(C2=NC=CC=N2)=NC=CC=N1.C3(C4=NC=CC=N4)=NC=CC=N3.C5(C6=NC=CC=N6)=NC=CC=N5.[Cl-].[Cl-].[Ru+2]

InChI

1S/3C8H6N4.2ClH.Ru/c3*1-3-9-7(10-4-1)8-11-5-2-6-12-8;;;/h3*1-6H;2*1H;/q;;;;;+2/p-2

InChI key

DVHNMJRXSLLELA-UHFFFAOYSA-L

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General description

[Ru(bpm)3][Cl]2 is used as a photoredox catalyst in direct methoxycyclization reactions.

Application

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

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Product No.
Description
Pricing

Pictograms

Health hazard
GHS08

Signal Word

Warning

Hazard Statements

H373

Precautionary Statements

P260 - P314 - P501

Hazard Classifications

STOT RE 2 Oral

Target Organs

Kidney

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Photoredox-assisted gold-catalyzed arylative alkoxycyclization of 1, 6-enynes
Mayans JG, et al.
Organic Letters, 22(8), 3045-3049 (2020)

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