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667900

Sigma-Aldrich

N-Boc-2-indolyldimethylsilanol

95%

Synonym(s):

2-(hydroxydimethylsilyl)-1,1-dimethylethylindole-1-carboxylic acid ester, N-Boc-indol-2-yldimethylsilanol

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About This Item

Linear Formula:
((C8H5N)(CO2C(CH3)3))Si(CH3)2(OH)
CAS Number:
784161-48-4
Molecular Weight:
291.42
MDL number:
MFCD08457643
UNSPSC Code:
12352100
PubChem Substance ID:
24884947
NACRES:
NA.22

Assay

95%

refractive index

n20/D 1.545

storage temp.

2-8°C

SMILES string

CC(C)(C)OC(=O)n1c(cc2ccccc12)[Si](C)(C)O

InChI

1S/C15H21NO3Si/c1-15(2,3)19-14(17)16-12-9-7-6-8-11(12)10-13(16)20(4,5)18/h6-10,18H,1-5H3

InChI key

ARJIKJGACIMUOM-UHFFFAOYSA-N

Application

A useful silicon nucleophile for Pd-catalyzed cross-coupling.
Reactant for:
Palladium-catalyzed cross-coupling reactions

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
01428TH
01825DE

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Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)

Articles

Organosilanols

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

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