633429
3,5-Dimethylpyrazole-1-carboxamidine hydrochloride, polymer-supported
100-200 mesh, extent of labeling: 1.0-2.0 mmol/g loading, 1 % cross-linked with divinylbenzene
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About This Item
crosslinking
1 % cross-linked with divinylbenzene
extent of labeling
1.0-2.0 mmol/g loading
particle size
100-200 mesh
InChI
1S/C6H10N4.Cl/c1-4-3-5(2)10(9-4)6(7)8;/h3H,1-2H3,(H3,7,8);
InChI key
VEBVDVIHRVPBQW-UHFFFAOYSA-N
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Application
Polymer-bound reagent for amidation of amines to make guanidines.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Peter Pogány et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(4), 1466-1473 (2008-06-20)
In the paper a joint experimental and theoretical study of 3,5-dimethyl-1H-pyrazole-1-carboxamidine (L) as well as its complexes CoL2(H2O)2(NO3)2 and NiL2(H2O)2(NO3)2 is reported. On the basis of FT-IR experiments and a DFT-derived scaled quantum mechanical force field the normal coordinate analysis
Antonia G Miller et al.
Annals of the New York Academy of Sciences, 1043, 195-200 (2005-07-23)
Protein cross-linking via the Maillard reaction with alpha-dicarbonyl compounds has been the subject of intense scrutiny in the literature. We report here a study of the impact of this cross-linking on enzyme function. Protein function following glycation was examined by
L Spero et al.
Biochimica et biophysica acta, 251(3), 345-356 (1971-12-28)
Guanidination of the free amino groups of staphylococcal enterotoxin B with 3,5-dimethyl-1-guanylpyrazole converted 31-32 of 33 epsilon-amino groups and 30% of the N-terminal residue. This product, although markedly reduced in solubility, suffered no gross change in conformation and retained full
A Bernhardt et al.
The journal of peptide research : official journal of the American Peptide Society, 50(2), 143-152 (1997-08-01)
Peptide-4-nitroanilides can be quickly synthesised using an Fmoc-based approach on 2-chlorotritylchloride resin. Preformed building blocks Fmoc-Xaa-NH-Np (Xaa = Cit, Cys, Gln, His, Lys, Orn, Ser, Thr, Tyr, Trp) can be attached via side chain to the 2-chlorotritylchloride linker of the
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