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464651

Sigma-Aldrich

Palladium

powder, <75 μm, 99.9% trace metals basis

Synonym(s):

Palladium (nanoparticles), Palladium (powder), Palladium black, Palladium element

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5 G
€631.00

About This Item

Linear Formula:
Pd
CAS Number:
Molecular Weight:
106.42
EC Number:
MDL number:
UNSPSC Code:
12141733
PubChem Substance ID:
NACRES:
NA.23

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Quality Level

Assay

99.9% trace metals basis

form

powder

resistivity

9.96 μΩ-cm, 20°C

particle size

<75 μm

bp

2970 °C (lit.)

mp

1554 °C (lit.)

density

12.02 g/cm3 (lit.)

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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This Item
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Palladium powder, &lt;75&#160;&#956;m, 99.9% trace metals basis

464651

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Palladium powder or granules, 99.99% trace metals basis

203998

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Palladium powder, 99.995% trace metals basis

203939

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Palladium foil, thickness 0.025&#160;mm, 99.9% trace metals basis

267120

Palladium

form

powder

form

powder or granules

form

powder

form

foil

mp

1554 °C (lit.)

mp

1554 °C (lit.)

mp

1554 °C (lit.)

mp

1554 °C (lit.)

resistivity

9.96 μΩ-cm, 20°C

resistivity

9.96 μΩ-cm, 20°C

resistivity

9.96 μΩ-cm, 20°C

resistivity

9.96 μΩ-cm, 20°C

bp

2970 °C (lit.)

bp

2970 °C (lit.)

bp

2970 °C (lit.)

bp

2970 °C (lit.)

density

12.02 g/cm3 (lit.)

density

12.02 g/cm3 (lit.)

density

12.02 g/cm3 (lit.)

density

12.02 g/cm3 (lit.)

Application

  • Laccases as palladium oxidases: This study introduces a coupled catalytic system involving an enzyme and a palladium(II) catalyst for the aerobic oxidation of alcohol, showcasing a novel application of palladium in green chemistry (Y Mekmouche et al., 2015).
  • Palladium-based nanomaterials: synthesis and electrochemical applications: Reviews the synthesis and utility of palladium-based nanomaterials, with a focus on their electrochemical applications, particularly in energy conversion and storage (A Chen, C Ostrom, 2015).
  • Strategies for sustainable palladium catalysis: Discusses the sustainability of palladium catalysis, including methods to recycle and reuse palladium and strategies to reduce the environmental impact of palladium sourcing (S McCarthy et al., 2021).

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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The Journal of organic chemistry, 78(8), 3783-3801 (2013-03-21)
Tetrahydrofurans and pyrrolidines are among the most important heterocycles found in bioactive compounds. Cyclization-functionalization domino reactions of alcohols or amines onto olefins constitute one of the most efficient methods to access them. In this context, oxy- and aminoalkynylation are especially
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A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.
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A novel Pd/Cu catalyzed domino reaction for the synthesis of functionalized pyrrolo[1,2-b]pyridazines from readily accessible (hetero)aryl propargyl alcohols and 1-amino-2-bromopyrroles was developed. This cascade process involves a Sonogashira cross-coupling reaction, an isomerization and an intramolecular condensation.
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The development of transition metal-catalysed cross-coupling reactions has greatly influenced the manner in which the synthesis of complex organic molecules is approached. A wide variety of methods are now available for the formation of C(sp(2))-C(sp(2)) bonds, and more recent work
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As novel therapeutic agents relevant to colon cancer therapy are explored continuously, we tested 4 R2edda-type ligand precursors O,O'-dialkyl esters of (S,S)-ethylenediamine-N,N'-di-2-(4-methyl)pentanoic acid (L1.2HCl-L4.2HCl) and corresponding palladium(II) and platinum(II) complexes against the human colon cancer cell lines CaCo-2, SW480 and

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