243493

Zirconium(IV) oxynitrate hydrate

• Synonym(s): Zirconyl nitrate hydrate
• Linear Formula: ZrO(NO₃)₂ · xH₂O
• CAS Number: 14985-18-3
• Molecular Weight: 231.23 (anhydrous basis)
• EC Number: 237-529-3
• MDL number: MFCD00149896
• UNSPSC Code: 12352302
• PubChem Substance ID: 24854506
• NACRES: NA.23
• form: powder and chunks

Properties

• form: powder and chunks
• Quality Level: 100
• composition: Degree of hydration, ~6
• color: white
• application(s): battery manufacturing
• SMILES string: O=[Zr++].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O
• InChI: 1S/2NO3.H2O.O.Zr/c2*2-1(3)4;;;/h;;1H2;;/q2*-1;;;+2
• InChI key: BGMQNYCWALSARE-UHFFFAOYSA-N

Description

General description

Zirconium(IV) oxynitrate hydrate is a crystalline zirconium compound that exhibits high solubility in water. It typically comprises amixture of oxide and a slightly hydroxide form.

Application

Zirconium(IV) oxynitrate hydrate is used to prepare CeO₂-ZrO₂ mixed oxide catalyst supports.[1] It may be used as zirconium precursor in the preparation of;

• Pb(Zr_0.50Ti_0.50)O₃ ferroelectric thin films,[2]
• silica- and alumina-doped nanocrystalline ceria/zirconia (Ce_0.5Zr_0.5O₂).[3]

Safety Information

• Pictograms: GHS03,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H272,H302,H314
• Precautionary Statements: P210 - P260 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B
• Supplementary Hazards: EUH071
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves