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200891

Sigma-Aldrich

Vanadium(V) oxychloride

99%

Synonym(s):

Trichlorooxovanadium oxide, Vanadium(V) oxytrichloride, Vanadyl trichloride

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100 G
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100 G
€56.70

About This Item

Linear Formula:
VOCl3
CAS Number:
Molecular Weight:
173.30
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
form:
liquid

€56.70


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Request a Bulk Order

vapor pressure

13.8 mmHg ( 20 °C)

Quality Level

Assay

99%

form

liquid

reaction suitability

reagent type: catalyst
core: vanadium

bp

126-127 °C (lit.)

mp

−77 °C (lit.)

density

1.84 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

Cl[V](Cl)(Cl)=O

InChI

1S/3ClH.O.V/h3*1H;;/q;;;;+3/p-3

InChI key

JBIQAPKSNFTACH-UHFFFAOYSA-K

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Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Masayuki Kirihara et al.
Chemical & pharmaceutical bulletin, 52(5), 625-627 (2004-05-11)
Thiols were converted into disulfide by the aerobic oxidation catalyzed by trichlorooxyvanadium in the presence of molecular sieves 3A.
[Hygienic characteristics of the working conditions in the manufacture of vanadium hydroxychloride].
B G Feĭgin et al.
Gigiena truda i professional'nye zabolevaniia, (1)(1), 51-52 (1985-01-01)
M D Zidan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56(14), 2693-2698 (2001-01-06)
A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the following heated salts NaF, KBr and KI

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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