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199923

Sigma-Aldrich

Lanthanum(III) oxide

99.99% trace metals basis

Synonym(s):

Dilanthanum trioxide, Lanthanum oxide, Lanthanum trioxide, Lanthanum(3+) oxide

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About This Item

Linear Formula:
La2O3
CAS Number:
1312-81-8
Molecular Weight:
325.81
EC Number:
215-200-5
MDL number:
MFCD00011071
UNSPSC Code:
12352303
PubChem Substance ID:
24851945
NACRES:
NA.23

Assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: lanthanum

density

6.51 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

O=[La]O[La]=O

InChI

1S/2La.3O

InChI key

KTUFCUMIWABKDW-UHFFFAOYSA-N

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General description

La2O3 is a wide band gap p-type semiconductor with an empty Ln-4f shell and is widely used to prepare optical materials, dielectrics, and conductive ceramics. La2O3 can also be used as a catalyst in many organic transformations.

Application

Lanthanum(III) oxide can be used as a dopant to prepare radiation-shielding glasses. For example, it can be added to waste soda-lime glass to improve the linear attenuation coefficient and radiation shielding characteristics of the glass.

It can be used as a recyclable catalytic system for the synthesis of diphenyl sulfides and selenides and for the C-N cross-coupling of aryl halides with heteroaromatic amines.

It can also be used as a promoter or support material for the selective oxidation of methanol over gold catalyst.
Precursor to LAMOX fast ion conductors and superconductors.

Features and Benefits

  • High refractive index
  • Low dispersion
  • Colorless in the glass matrix
  • Efficient, inexpensive, and recyclable catalyst

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Lili Liu et al.
Journal of nanoscience and nanotechnology, 11(3), 2155-2162 (2011-04-01)
La2O3-CeO2 nanopowders with different La2O3 (0-20 mol%) were prepared by the sol-gel method. The modification of the cubic structure of ceria by substituting La3+ for Ce4+ into the lattice of CeO2 has been investigated. The crystal structure of La2O3-CeO2 nanomaterials
A J Barón-González et al.
Journal of physics. Condensed matter : an Institute of Physics journal, 23(49), 496003-496003 (2011-11-24)
The origin of dielectric anomalies and magnetodielectric response of La(2)MnCoO(6) has been investigated by means of ultra-high resolution synchrotron x-ray powder diffraction, neutron powder diffraction, resistivity, magnetization and dielectric measurements. The study has been performed on two different bulk samples
Lukas C Gerber et al.
Chemical communications (Cambridge, England), 48(32), 3869-3871 (2012-03-14)
Lanthanum oxide nanoparticles were utilized to scavenge phosphate from microbial growth media for the use of targeted nutrient starvation as an antimicrobial strategy. Only in phosphate poor environments a toxic effect was observed. The effect was shown on Escherichia coli
A K Singh et al.
Optics letters, 37(5), 776-778 (2012-03-02)
Low-power-threshold cw laser-induced incandescence (CWLII) has been observed in La(2)O(3):Er(3+)-Yb(3+) phosphor on excitation by a 976 nm IR laser. It is suggested that incandescence originates from the extensive heating induced by the nonradiative processes taking place following the laser excitation.
Amel Amirouche-Korichi et al.
Dental materials : official publication of the Academy of Dental Materials, 25(11), 1411-1418 (2009-08-18)
The degree of conversion (DC) and polymerization shrinkage of resin composites are closely related manifestations of the same process. Ideal dental composite would show an optimal degree of conversion and minimal polymerization shrinkage. These seem to be antagonistic goals, as
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