109576
1,1′-Dimethylferrocene
95%
Synonym(s):
Bis(methylcyclopentadienyl)iron
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About This Item
Empirical Formula (Hill Notation):
C12H14Fe
CAS Number:
Molecular Weight:
214.08
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
95%
form
solid
reaction suitability
core: iron
reagent type: catalyst
mp
37-40 °C (lit.)
SMILES string
[Fe].C[C]1[CH][CH][CH][CH]1.C[C]2[CH][CH][CH][CH]2
InChI
1S/2C6H7.Fe/c2*1-6-4-2-3-5-6;/h2*2-5H,1H3;
InChI key
GJFIEPAJMYPAGC-UHFFFAOYSA-N
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
226.4 °F - closed cup
Flash Point(C)
108.00 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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P C Pandey et al.
Analytical biochemistry, 252(1), 136-142 (1997-11-05)
This article describes the research investigations on the development of the amperometric biosensors based on mediated bioelectrochemistry. The mediated bioelectrochemistry involving horseradish peroxidase and glucose oxidase within the graphite paste is reported. The enzyme horseradish peroxidase together with electrochemical mediator
J H Luong et al.
Journal of molecular recognition : JMR, 8(1-2), 132-138 (1995-01-01)
Inclusion complexes of 1,1'-dimethylferrocene (DMFe) with alpha-, 2-hydroxypropyl-beta- or gamma-cyclodextrins were formed in aqueous systems. For the first time, the interacting DMFe-cyclodextrin systems have been characterized using cyclic voltammetry which enabled the estimation of the complexation order, the formation constant
K B Male et al.
Applied biochemistry and biotechnology, 44(1), 91-100 (1994-01-01)
Water-soluble 2-hydroxypropyl-beta-cyclodextrin (Hp-beta-CyD), a cyclic and nonreducing oligosaccharide was used to enclose a hydrophobic guest molecule 1,1'-dimethylferrocene (DMF) to form a water-soluble yellow complex. At high concentrations (300 mM), Hp-beta-CyD enclosed up to 100 mM DMF. The yellow complex was
D J Claremont et al.
Diabetologia, 29(11), 817-821 (1986-11-01)
Miniature, amperometric glucose sensors were constructed using entrapped 1,1'-dimethylferrocene to mediate electron transfer between immobilised glucose oxidase and a carbon base electrode. Electrodes were calibrated in buffered glucose solutions and then implanted in the subcutaneous tissue of anaesthetised, non-diabetic pigs.
J H Luong et al.
Analytical biochemistry, 212(1), 269-276 (1993-07-01)
Water-soluble 2-hydroxypropyl-beta-cyclodextrin (hp-beta-CyD), a cyclic and nonreducing oligosaccharide, was used to enclose the hydrophobic guest molecules ferrocene (FeCp2) and 1,1'-dimethylferrocene (DMFeCp2) to form a water-soluble complex. At high concentrations (300 mM), hp-beta-CyD enclosed up to 100 mM FeCp2 or DMFeCp2.
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