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USP HPLC Organic Impurity Analysis for Lamotrigine Tablets (SST) on an Ascentis® Express C18

USP HPLC Organic Impurity Analysis for Lamotrigine Tablets (SST) on an Ascentis® Express C18

Materialien

Analytische Säule

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Ascentis® Express C18, 5 μm HPLC Column

5 μm particle size, L × I.D. 25 cm × 4.6 mm

Komponente der mobilen Phase

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Lamotrigin-verwandte Verbindung C

United States Pharmacopeia (USP) Reference Standard

Acetonitril

isocratic grade for liquid chromatography LiChrosolv®

Methanol

for liquid chromatography LiChrosolv®

Ammoniumacetat

for HPLC LiChropur

Wasser

for chromatography (LC-MS Grade) LiChrosolv®

Probenvorb.

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Millex®-PVDF-Spritzenvorsatzfilter

pore size 0.45 μm, diam. 33 mm, non-sterile, hydrophilic

Standard

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Lamotrigin

United States Pharmacopeia (USP) Reference Standard

Lamotrigin-verwandte Verbindung B

United States Pharmacopeia (USP) Reference Standard

CONDITIONS

column

Ascentis® Express C18, 250 x 4.6 mm I.D., 5 µm (50538-U)

mobile phase

Acetonitrile:methanol:buffer (10:30:60) v/v/v; Buffer– 0.8 g/L of ammonium acetate, adjusted with glacial acetic acid to a pH of 4.5

gradient

Isocratic

flow rate

1 mL/min

pressure

216 bar (3132 psi)

column temp.

Ambient

detector

UV, 210 nm

injection

5 µL

sample/matrix

System suitability solution - 1.0 µg/mL of lamotrigine related compound B and 0.4 mg/ml of lamotrigine in methanol and buffer (60:40) v/v

Beschreibung

Allgemeine Beschreibung

Lamotrigine is an anti-convulsant medication used to treat epilepsy and to delay or prevent the recurrence of depressive episodes in bipolar disorder. For epilepsy, this includes focal seizures, tonic-clonic seizures, and seizures in Lennox-Gastaut syndrome.
In bipolar disorder, lamotrigine has not been shown to reliably treat acute depression, but for patients with bipolar disorder who are not currently symptomatic, it appears to be effective in reducing the risk of future episodes of depression.
This application illustrated the system suitability for the organic impurity analysis for lamotrigine tablets testing following the currently official United States Pharmacopoeia monograph

Hinweis zur Analyse

For the lamotrigine standard solution, the RSD was 0.43 (USP specification NMT 10% RSD) and the tailing factor for lamotrigine was 1.7 (USP specification NMT 2). For the displayed system suitability solution the resolution between lamotrigine and the related compound B was 2.6 (USP specification NLT 2.0).

Sonstige Hinweise

App_367I

Rechtliche Hinweise

Ascentis is a registered trademark of Merck KGaA, Darmstadt, Germany