GC Analysis of Sulfur Compounds in Gasoline on SPB®-1 SULFUR
Materialien
Analytische Säule
CONDITIONS
column
SPB-1 SULFUR, 30 m x 0.32 mm I.D., 4.0 μm (24158)
oven
35 ºC, 5 ºC/min to 200 ºC
inj. temp.
275 °C
detector
FID, 300 ºC; FPD, 300 ºC
carrier gas
helium, 20 cm/sec
injection
1 μL 100:1 split
sample
Gasoline
Beschreibung
Hinweis zur Analyse
Two issues must be overcome for the analysis of sulfur compounds in fuels. 1) Detection of these compounds in a hydrocarbon sample matrix, and 2) adsorption of these compounds by the column. Sulfur specific detectors, such as a flame photometric detector (FPD), can be used to overcome the first challenge. A low phase ratio column, such as the SPB-1 SULFUR, can be used to overcome the second challenge. This slide shows the analysis of a gasoline sample, in which the column effluent was split to two detectors. The top chromatogram shows the FID response, and the bottom chromatogram shows the FPD response.
Rechtliche Hinweise
SPB is a registered trademark of Merck KGaA, Darmstadt, Germany