CRM69083
Dinoseb
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonym(e):
2-sec-Butyl-4,6-dinitrophenol
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About This Item
Empirische Formel (Hill-System):
C10H12N2O5
CAS-Nummer:
Molekulargewicht:
240.21
MDL-Nummer:
UNSPSC-Code:
41116107
NACRES:
NA.24
Empfohlene Produkte
Qualität
certified reference material
TraceCERT®
Qualitätsniveau
Produktlinie
TraceCERT®
Haltbarkeit
limited shelf life, expiry date on the label
Hersteller/Markenname
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Format
neat
Lagertemp.
2-8°C
SMILES String
CCC(C)c1cc(cc(c1O)[N+]([O-])=O)[N+]([O-])=O
InChI
1S/C10H12N2O5/c1-3-6(2)8-4-7(11(14)15)5-9(10(8)13)12(16)17/h4-6,13H,3H2,1-2H3
InChIKey
OWZPCEFYPSAJFR-UHFFFAOYSA-N
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Allgemeine Beschreibung
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Dinoseb is a selective nitrophenolic herbicide used for protection against postemergence of grass and broad-leaf weeds in vegetables, fruits, nuts, and other field crops such as soybeans. In addition, it also finds its use as an insecticide for grapes, and as a seed drying agent. It acts by uncoupling oxidative phosphorylation in mitochondria and inhibiting ATP synthesis.
Under the Regulation (EC) No 1107/2009 and withdrawing the Council Directives 79/117/EEC and 91/414/EEC, dinoseb is not approved for its use as a plant protection product in the European Union (EU). It was also banned for use as a pesticide in the US in 1986 by the US EPA (Environmental Protection Agency). But a default maximum residue limit (MRL) in the range of 0.02 mg/kg to 0.1 mg/kg is set for the presence of dinoseb (measured as a sum of dinoseb, its salts, dinoseb-acetate, and binapacryl) in products of plant and animal origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Dinoseb is a selective nitrophenolic herbicide used for protection against postemergence of grass and broad-leaf weeds in vegetables, fruits, nuts, and other field crops such as soybeans. In addition, it also finds its use as an insecticide for grapes, and as a seed drying agent. It acts by uncoupling oxidative phosphorylation in mitochondria and inhibiting ATP synthesis.
Under the Regulation (EC) No 1107/2009 and withdrawing the Council Directives 79/117/EEC and 91/414/EEC, dinoseb is not approved for its use as a plant protection product in the European Union (EU). It was also banned for use as a pesticide in the US in 1986 by the US EPA (Environmental Protection Agency). But a default maximum residue limit (MRL) in the range of 0.02 mg/kg to 0.1 mg/kg is set for the presence of dinoseb (measured as a sum of dinoseb, its salts, dinoseb-acetate, and binapacryl) in products of plant and animal origin.
Anwendung
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The dinoseb CRM may also be used to:
The dinoseb CRM may also be used to:
- Simultaneously determine dinoseb and pendimethalin in surface water samples using optimized direct injection (DI) and solid phase extraction (SPE) coupled to ultra high-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS)
- Evaluate anodic voltametric analysis of dinoseb in river water samples using a boron doped diamond electrode following cathode pre-treatment and in the presence of cationic surfactants
- Extract 15 phenols from refinery wastewater samples by dispersive liquid-liquid microextraction (DLLME) technique and identify them by liquid chromatography-photodiode array detector (LC-PDA)
- Detect chlorophenoxy acid methyl esters and other chlorinated herbicides in peppermint tea, plum, and orange peel extract soft ionization gas chromatography coupled to quadrupole time-of-flight mass spectrometry (GC-QTOFMS)
- Analyze 32 pesticide residues of four different chemical classes in tea brew and tea leaves samples by a sample treatment method based on metabolomics and liquid chromatography-mass spectrometry (LC-MS)
- Determine pendimethalin, dinoseb and sodium 5-nitroguaiacolate in vegetable samples by differential pulse voltammetry (DPV) and chemometrics
Empfohlene Produkte
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Rechtliche Hinweise
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Signalwort
Danger
Gefahreneinstufungen
Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Repr. 1B - Skin Irrit. 2 - Skin Sens. 1
Zusätzliche Gefahrenhinweise
Lagerklassenschlüssel
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flammpunkt (°F)
306.9 °F - closed cup
Flammpunkt (°C)
152.7 °C - closed cup
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Analysenzertifikate (COA)
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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.
Viorica Lopez-Avila et al.
Analytical chemistry insights, 10, 1-9 (2015-02-24)
Gas chromatography with quadrupole time-of-flight mass spectrometry (GC-QTOFMS) and soft ionization generated by a rare-gas plasma is described here for the determination of various chlorophenoxy acid methyl esters and a few chlorinated herbicides. This plasma-based, wavelength-selectable ionization source, which can
Mathieu Cladière et al.
Food chemistry, 242, 113-121 (2017-10-19)
This study attempts at uniting the analysis of four different classes of contaminants for both liquid and solid tea samples. A total of 32 compounds, classified as pesticides, mycotoxins, process-induced toxicants or packaging contaminants, were carefully chosen for their diversity
Yongnian Ni et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 46(4), 328-335 (2011-04-23)
A novel differential pulse voltammetry method (DPV) was researched and developed for the simultaneous determination of Pendimethalin, Dinoseb and sodium 5-nitroguaiacolate (5NG) with the aid of chemometrics. The voltammograms of these three compounds overlapped significantly, and to facilitate the simultaneous
Mariko Matsumoto et al.
Reproductive toxicology (Elmsford, N.Y.), 25(3), 327-334 (2008-05-09)
The present review paper summarizes the data available in the literature concerning prenatal exposure to dinoseb (2-sec-butyl-4,6-dinitrophenol; CAS No. 88-85-7), evaluating reported developmental toxicity in experimental animals. In particular, we have focused on the variable factors in the manifestation of
Mark R Viant et al.
Aquatic toxicology (Amsterdam, Netherlands), 77(4), 359-371 (2006-02-21)
Pesticide pulses in the Sacramento River, California, originate from storm-water discharges and non-point source aquatic pollution that can last from a few days to weeks. The Sacramento River and its tributaries have historically supported the majority of California's Chinook salmon
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