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2-Bromacetophenon

for GC derivatization, LiChropur™, ≥99.0%

Synonym(e):

ω-Bromacetophenon, Phenacylbromid

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About This Item

Lineare Formel:
C6H5COCH2Br
CAS-Nummer:
70-11-1
Molekulargewicht:
199.04
Beilstein:
606474
EG-Nummer:
200-724-9
MDL-Nummer:
MFCD00000195
UNSPSC-Code:
12000000
PubChem Substanz-ID:
329767691
NACRES:
NA.22

Qualität

for GC derivatization
LiChropur™

Qualitätsniveau

100

Assay

≥99.0% (GC)
≥99.0%

Form

crystals

Eignung der Reaktion

reagent type: derivatization reagent
reaction type: Acylations

Methode(n)

gas chromatography (GC): suitable

bp

135 °C/18 mmHg (lit.)

mp (Schmelzpunkt)

48-51 °C (lit.)
49-50 °C

Lagertemp.

2-8°C

SMILES String

BrCC(=O)c1ccccc1

InChI

1S/C8H7BrO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2

InChIKey

LIGACIXOYTUXAW-UHFFFAOYSA-N

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Allgemeine Beschreibung

2-Bromoacetophenone is a commonly used derivatization agent for fatty acid detection in biological samples.

Anwendung

Herstellung von kristallinen Estern aus Säuren

Rechtliche Hinweise

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Piktogramme

Corrosion
GHS05

Signalwort

Danger

H-Sätze

H314

Gefahreneinstufungen

Skin Corr. 1B

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

235.4 °F - closed cup

Flammpunkt (°C)

113 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Choose from one of the most recent versions:

Analysenzertifikate (COA)

Lot/Batch Number
BCCG1542
BCBG9218V
BCBG9218V
1279526V
1279526

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2-Brom-4′-methoxy-acetophenon 97%

Sigma-Aldrich

115665

2-Brom-4′-methoxy-acetophenon

2-Brom-2′-acetonaphthon 99%

Sigma-Aldrich

105120

2-Brom-2′-acetonaphthon

Phenylacetylen 98%

Sigma-Aldrich

117706

Phenylacetylen

2-Chlor-acetophenon 98%

Sigma-Aldrich

C19686

2-Chlor-acetophenon

High-performance liquid chromatography of fatty acids in biological samples.
Lima ES and Abdalla DSP
Analytica Chimica Acta, 465(1-2), 81-91 (2002)
S Ramalingam et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(2), 826-834 (2011-01-11)
In this work, the experimental and theoretical spectra of 4-chloro-2-bromoacetophenone (4C2BAP) are studied. FT-IR and FT-Raman spectra of title molecule have been recorded in the region 4000-100 cm(-1). The structural and spectroscopic data of the molecule in the ground state
A Kanstrup et al.
Archives of biochemistry and biophysics, 304(2), 332-337 (1993-08-01)
A series of 18 phenacyl bromide and iodoacetamide analogues have been synthesized and used to alkylate Met-398 situated in the S'1 binding site of carboxypeptidase Y. The course of the reactions was monitored by measurements of the peptidase and esterase
Anabha E Raveendran et al.
Organic & biomolecular chemistry, 8(4), 901-905 (2010-02-06)
Nucleophilic heterocyclic carbenes (NHCs) have been used for the first time as catalysts in the cyclopropanation of ethyl cyanocinnamates with phenacyl bromide by Michael-initiated ring-closure (MIRC).
P A Wender et al.
Organic letters, 1(13), 2117-2120 (2000-06-03)
[formula: see text] 4'-Bromoacetophenone derivatives which upon excitation can generate monophenyl radicals capable of hydrogen atom abstraction were investigated as photoinducible DNA cleaving agents. Pyrrolecarboxamide-conjugated 4'-bromoacetophenones were synthesized, and their DNA cleaving activities and sequence selectivities were determined.
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