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Merck

35620

Supelco

2,6-Dichlor-chinon-4-chlorimid

for spectrophotometric det. of vitamin B6, ≥99.0%

Synonym(e):

N,2,6-Trichlor-p-benzochinonimid, Gibbs Reagens

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About This Item

Empirische Formel (Hill-System):
C6H2Cl3NO
CAS-Nummer:
Molekulargewicht:
210.45
Beilstein:
2364249
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
41116105
PubChem Substanz-ID:
NACRES:
NA.21

Qualitätsniveau

Assay

≥99.0% (AT)
≥99.0%

Qualität

for spectrophotometric det. of vitamin B6

Methode(n)

UV/Vis spectroscopy: suitable

mp (Schmelzpunkt)

65-67 °C (lit.)
65-68 °C

Anwendung(en)

food and beverages
vitamins, nutraceuticals, and natural products

Lagertemp.

2-8°C

SMILES String

Cl\N=C1\C=C(Cl)C(=O)C(Cl)=C1

InChI

1S/C6H2Cl3NO/c7-4-1-3(10-9)2-5(8)6(4)11/h1-2H

InChIKey

YHUMTHWQGWPJOQ-UHFFFAOYSA-N

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Allgemeine Beschreibung

2,6-Dichloroquinone-4-chloroimide generally find application in being used as spot test and chromatographic spray reagents, mainly for phenols, though it can be used in detection of other types of compounds such as antioxidants, few primary and secondary amines, on silica gel chromatographic plates. Its decomposition rate is directly proportional to pressure.

Anwendung

Gibb′s reagent was used in paper chromatography, in an experiment conducted to semi-quantitatively estimate tyramine and octopamine.

Piktogramme

FlameExclamation mark

Signalwort

Danger

Gefahreneinstufungen

Eye Irrit. 2 - Self-react. C - Skin Irrit. 2

Lagerklassenschlüssel

4.1A - Other explosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Occurrence and some properties of eledoisin in extracts of posterior salivary glands of Eledone.
Anastasi A and Erspamer V.
British Journal of Pharmacology and Chemotherapy, 19 (2), 326-336 (1962)
2, 6-Dichloroquinone 4-chloroimide as a reagent for amines and aromatic hydrocarbons on thin-layer chromatograms.
Hansbro RJ
Analytical Chemistry, 40 (14), 2138-2143 (1968)
Colour reaction of phenols with the gibbs reagent. The reaction mechanism and decomposition and stabilisation of the reagent.
Svobodova D
Microchimica Acta, 67 (3-4), 251-264 (1977)
I L Tsai et al.
Planta medica, 66(5), 403-407 (2000-07-26)
Four new cytotoxic neolignans, machilusol A (1), machilusol C (3), machilusol D (4), machilusol E (5) as well as two new inactive neolignans, machilusol B (2) and machilusol F (6), were isolated from the stem wood of Machilus obovatifolia. All
N A El-Ragehy et al.
Journal of pharmaceutical and biomedical analysis, 29(1-2), 121-137 (2002-06-14)
Six procedures have been suggested for the determination of the antihistaminic agent, mequitazine, in the presence of its degradate. Mequitazine, having a phenothiazine group, undergoes peroxide oxidation and the corresponding sulphone is produced. Its identity was confirmed by IR and

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