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Merck

31562

Supelco

Disulfoton-sulfoxid

PESTANAL®, analytical standard

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About This Item

Empirische Formel (Hill-System):
C8H19O3PS3
CAS-Nummer:
Molekulargewicht:
290.40
Beilstein:
1712528
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
41116107
PubChem Substanz-ID:
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

Produktlinie

PESTANAL®

Haltbarkeit

limited shelf life, expiry date on the label

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Anwendung(en)

agriculture
environmental

Format

neat

Lagertemp.

2-8°C

SMILES String

CCOP(=S)(OCC)SCCS(=O)CC

InChI

1S/C8H19O3PS3/c1-4-10-12(13,11-5-2)14-7-8-15(9)6-3/h4-8H2,1-3H3

InChIKey

UPUGLJYNCXXUQV-UHFFFAOYSA-N

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Allgemeine Beschreibung

Disulfoton-sulfoxide is one of the oxidative metabolites of disulfoton, an organophosphorus insecticide used against aphids, mites, and thrips.

Anwendung

Disulfoton-sulfoxide may be used as a reference standard for the determination of the analyte:
  • In human biological samples based on QuEChERS (Quick, Easy, Cheap, Effective, Rugged, and Safe) extraction and liquid chromatography–tandem mass spectrometry.
  • In cereal-based baby foods and wheat flour using hollow-fiber liquid-phase microextraction prior to gas chromatography with nitrogen phosphorus detection.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Rechtliche Hinweise

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Piktogramme

Skull and crossbonesEnvironment

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 1 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Analysenzertifikate (COA)

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Determination of organophosphorus pesticides and metabolites in cereal-based baby foods and wheat flour by means of ultrasound-assisted extraction and hollow-fiber liquid-phase microextraction prior to gas chromatography with nitrogen phosphorus detection.
Gonzalez-Curbelo MA, et al.
Journal of Chromatography A, 1313(6), 166-174 (2013)
Yasuhisa Fujino et al.
Chudoku kenkyu : Chudoku Kenkyukai jun kikanshi = The Japanese journal of toxicology, 17(3), 273-277 (2004-10-22)
We encountered three cases of organophosphate poisoning treated with pralidoxime iodide (PAM) and whole-bowel irrigation without atropine sulfate. All patients recovered without persistence or recurrence of toxic symptoms and without any somatic after effects. In case 1, a 48-year-old woman
Rapid determination of disulfoton and its oxidative metabolites in human whole blood and urine using QuEChERS extraction and liquid chromatography-tandem mass spectrometry.
Usui K, et al.
Legal medicine, 14(6), 309-316 (2012)
B Dementi
Journal of applied toxicology : JAT, 14(2), 119-129 (1994-03-01)
Many publications, primarily of work performed in Japan, report findings in human populations of an increased incidence of myopia and of a more advanced visual disease syndrome (Saku disease), which reportedly correlated with increasing use of organophosphate pesticides in agriculture.
Jishi Wang et al.
Journal of chromatography. A, 1521, 10-18 (2017-09-25)
In this research, the manual two-step QuEChERS approach has been streamlined and automated into a one-step method using a cleanup tube fitted within an extraction tube. A novel automatic QuEChERS combination have been developed to simplify the QuEChERS procedures and

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