86652

Tetraethylammonium(meta)periodat

technical, moistened with water, ≥90% (calc. based on dry substance, RT)

• Synonym(e): N,N,N-Triethylethanaminium salt with periodic acid
• Lineare Formel: (C₂H₅)₄N(IO₄)
• CAS-Nummer: 5492-69-3
• Molekulargewicht: 321.15
• Beilstein: 4166132
• EG-Nummer: 226-824-2
• MDL-Nummer: MFCD00043182
• UNSPSC-Code: 12352000
• PubChem Substanz-ID: 57653063
• NACRES: NA.22

Eigenschaften

• Qualität: technical; moistened with water
• Assay: ≥90% (calc. based on dry substance, RT)
• Form: crystals
• Enthält: ~10% water as stabilizer
• Eignung der Reaktion: reagent type: oxidant
• mp (Schmelzpunkt): ~170 °C (dec.)
• SMILES String: [O-]I(=O)(=O)=O.CC[N+](CC)(CC)CC
• InChI: 1S/C8H20N.HIO4/c1-5-9(6-2,7-3)8-4;2-1(3,4)5/h5-8H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
• InChIKey: YXYPONURGKGPDV-UHFFFAOYSA-M

Beschreibung

Anwendung

Reactant for intramolecular cycloaddition reactions

Tetraethylammonium (meta)periodate can be used as an oxidant in the N-dealkylation of tertiary amines using Fe(III) complex as a catalyst. It can also be employed as a reagent in the intramolecular cycloaddition reactions.

Sonstige Hinweise

Oxidant for use in organic solvents; Oxidation of 1,2-diols and olefins

Sicherheitshinweise

• Piktogramme: GHS02
• Signalwort: Danger
• H-Sätze: H228
• P-Sätze: P210
• Gefahreneinstufungen: Flam. Sol. 1
• Lagerklassenschlüssel: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)