717282

Chloro-[tri-(p-tolyl)-phosphin]-gold(I)

97%

• Synonym(e): Chloro-[tri-(4-methylphenyl)-phosphin]-gold(I)
• Empirische Formel (Hill-System): C₂₁H₂₁AuClP
• CAS-Nummer: 28978-10-1
• Molekulargewicht: 536.78
• MDL-Nummer: MFCD15144864
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 329763472

Eigenschaften

• Assay: 97%
• Form: powder
• Eignung der Reaktion: core: gold; reagent type: catalyst
• mp (Schmelzpunkt): 205-210 °C
• SMILES String: Cl[Au].Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc(C)cc3
• InChI: 1S/C21H21P.Au.ClH/c1-16-4-10-19(11-5-16)22(20-12-6-17(2)7-13-20)21-14-8-18(3)9-15-21;;/h4-15H,1-3H3;;1H/q;+1;/p-1
• InChIKey: QHHGSPBDJCGVPV-UHFFFAOYSA-M

Beschreibung

Anwendung

Gold Catalysts — 21st Century ′Gold Rush′

Reactant fro synthesis of:

• Phosphine-gold(I) derivatives
• Stable organogold(I) compound - catalyst for cyclization
• Gold(I) acetylide complexes
• Heterometallic gold(I)-rhenium(I) alkynyl complexes

Involved in reactions with unsaturated dimolybdenum anions

Reactant for oxidative addition of iodine to gold(I) complexes

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 1
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable