712892

(S)-(−)-2-(Dibenzylamino)propionaldehyd

97%

• Synonym(e): (S)-2-(Dibenzylamino)-propanal, N,N-Dibenzyl-L-alaninal
• Empirische Formel (Hill-System): C₁₇H₁₉NO
• CAS-Nummer: 111060-63-0
• Molekulargewicht: 253.34
• Beilstein: 4293933
• MDL-Nummer: MFCD11053600
• UNSPSC-Code: 12352114
• PubChem Substanz-ID: 329763158
• NACRES: NA.22

Eigenschaften

• Assay: 96.5-103.5% (NT); 97%
• Form: crystals
• Optische Aktivität: [α]/D -36.0±2.0°, c = 1 in ethanol
• Funktionelle Gruppe: aldehyde; amine; phenyl
• Lagertemp.: 2-8°C
• SMILES String: C[C@@H](C=O)N(Cc1ccccc1)Cc2ccccc2
• InChI: 1S/C17H19NO/c1-15(14-19)18(12-16-8-4-2-5-9-16)13-17-10-6-3-7-11-17/h2-11,14-15H,12-13H2,1H3/t15-/m0/s1
• InChIKey: GFYXFRCVQSKSDO-HNNXBMFYSA-N

Beschreibung

Anwendung

(S)-(-)-2-(Dibenzylamino)propionaldehyde can be employed as a building block for the preparation of:

• Linezolid dipeptide derivatives and 3-oxazolidin-2-one analogs.
• (2R,3S)-3-Dibenzylamine-1-nitrobutan-2-ol by reacting with bromonitromethane via nitro-aldol reaction using SmI₂ as a catalyst.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H302,H317
• P-Sätze: P261 - P264 - P272 - P280 - P301 + P312 - P302 + P352
• Gefahreneinstufungen: Acute Tox. 4 Oral - Skin Sens. 1
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Faceshields, Gloves