708763

[(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II)chlorid

• Synonym(e): [PdCl₂{(S)-4-tolylbinap}]
• Empirische Formel (Hill-System): C₄₈H₄₀Cl₂P₂Pd
• CAS-Nummer: 215597-19-6
• Molekulargewicht: 856.10
• MDL-Nummer: MFCD11656205
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329762823

Eigenschaften

• Form: solid
• mp (Schmelzpunkt): >300 °C
• Funktionelle Gruppe: phosphine
• SMILES String: Cl[Pd]Cl.Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8
• InChI: 1S/C48H40P2.2ClH.Pd/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;;;/h5-32H,1-4H3;2*1H;/q;;;+2/p-2
• InChIKey: ADMKISPNGKUJAU-UHFFFAOYSA-L

Beschreibung

Anwendung

Catalyst for:

• Stereoselective preparation of hydroxymethyldihydronaphthalenone via alkylative ring opening of oxabenzonorbornadiene with (PhMe2SiCH2)2Zn followed by hydrogenation and Tamao-Fleming oxidation
• Asymmetric synthesis of cyclopentylindanes via cyclization of bromo- and trifluoromethanesulfonyloxyphenylheptenylmalonate

Sicherheitshinweise

• Lagerklassenschlüssel: 13 - Non Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)