701718
2-Azaadamantan-N-oxyl
90%
Synonym(e):
AZADO
Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise
Alle Fotos(3)
About This Item
Empirische Formel (Hill-System):
C9H14NO
CAS-Nummer:
Molekulargewicht:
152.21
MDL-Nummer:
UNSPSC-Code:
12352000
PubChem Substanz-ID:
NACRES:
NA.22
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Assay
90%
Form
powder
Eignung der Reaktion
reagent type: oxidant
mp (Schmelzpunkt)
182-189 °C (D)
Lagertemp.
2-8°C
SMILES String
[O]N1[C@@H]2C[C@H]3C[C@@H](C2)C[C@@H]1C3
InChI
1S/C9H14NO/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2/t6-,7+,8-,9+
InChIKey
BCJCJALHNXSXKE-SPJNRGJMSA-N
Verwandte Kategorien
Allgemeine Beschreibung
2-Azaadamantane-N-oxyl (AZADO), a stable nitroxyl radical, is widely employed as catalyst for the oxidation of alcohols.
Anwendung
2-Azaadamantane-N-oxyl (AZADO) may be employed in the following studies:
- As catalyst for the oxidation of wood cellulose.
- As catalyst in the total synthesis of Yaku′amide A, a potential cytotoxin obtained from sponge Ceratopsion sp.
- As oxidant for the oxidation of (S)-glycidol.
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Masatoshi Shibuya et al.
Journal of the American Chemical Society, 128(26), 8412-8413 (2006-06-29)
Development of a stable nitroxyl radical class of catalysts, 2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO, for highly efficient oxidation of alcohols is described. AZADO and 1-Me-AZADO exhibit superior catalytic proficiency to TEMPO, converting various sterically hindered alcohols to the corresponding carbonyl
Ming Zhang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(10), 3937-3941 (2015-01-22)
An increased supply of scarce or inaccessible natural products is essential for the development of more sophisticated pharmaceutical agents and biological tools, and thus the development of atom-economical, step-economical and scalable processes to access these natural products is in high
Takefumi Kuranaga et al.
Journal of the American Chemical Society, 135(14), 5467-5474 (2013-03-19)
Here we report the first total synthesis and the complete stereochemical assignment of yaku'amide A. Yaku'amide A (1) was isolated from a sponge Ceratopsion sp. as an extremely potent cytotoxin. Its structure was determined except for the C4-stereochemistry in the
Takuya Isogai et al.
Biomacromolecules, 11(6), 1593-1599 (2010-05-18)
Curdlan, amylodextrin, and regenerated cellulose fiber were subjected to electromediated oxidation with a 4-acetamido-TEMPO catalyst in a buffer at pH 6.8 without NaClO or NaClO(2). More than 90% of the C6 primary hydroxyls of Curdlan and amylodextrin were converted to
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