676675

(+)-9-(1S, 2S-Pseudoephedrinyl)-(10R)-(trimethylsilyl)-9-borabicyclo[3.3.2]decan

• Synonym(e): N-Methyl-[1-methyl-2-phenyl-2-(10-trimethylsilanyl-9-borabicyclo[3.3.2]dec-9-yloxy)-ethylamin]
• Empirische Formel (Hill-System): C₂₂H₃₈BNOSi
• CAS-Nummer: 848618-13-3
• Molekulargewicht: 371.44
• MDL-Nummer: MFCD09265094
• UNSPSC-Code: 12352000
• PubChem Substanz-ID: 24885323

Eigenschaften

• Form: solid
• Optische Aktivität: [α]22/D +60°, c = 4.5 in chloroform-d
• mp (Schmelzpunkt): 130-134 °C
• SMILES String: CN[C@@H](C)[C@@H](OB1C2CCCC(CCC2)[C@@H]1[Si](C)(C)C)c3ccccc3
• InChI: 1S/C22H38BNOSi/c1-17(24-2)21(18-11-7-6-8-12-18)25-23-20-15-9-13-19(14-10-16-20)22(23)26(3,4)5/h6-8,11-12,17,19-22,24H,9-10,13-16H2,1-5H3/t17-,19-,20+,21+,22-/m0/s1
• InChIKey: ZOZYQBFBLCMBTA-RXZUFOQRSA-N

Beschreibung

Anwendung

Soderquist Reagents: For allylboration, allenylboration, propargylboration

Air-stable, crystalline pseudoephedrine borinic acid complex which when treated with an appropriate Grignard reagent provides access to homoallylic or homopropargylic alcohols and α-allenyl carbinols.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves