569763

(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinon -monohydrochlorid

97%

• Empirische Formel (Hill-System): C₁₃H₁₈N₂O · HCl
• CAS-Nummer: 278173-23-2
• Molekulargewicht: 254.76
• MDL-Nummer: MFCD03426983
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24880521
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: solid
• Optische Aktivität: [α]20/D -67°, c = 1 in H₂O
• mp (Schmelzpunkt): 157-161 °C (lit.)
• Funktionelle Gruppe: phenyl
• SMILES String: Cl.CN1C(=O)[C@H](Cc2ccccc2)NC1(C)C
• InChI: 1S/C13H18N2O.ClH/c1-13(2)14-11(12(16)15(13)3)9-10-7-5-4-6-8-10;/h4-8,11,14H,9H2,1-3H3;1H/t11-;/m0./s1
• InChIKey: YIYFEXGDFJLJGM-MERQFXBCSA-N

Beschreibung

Anwendung

Metal-free OrganoCatalyst technology for asymmetric catalysis. Catalyzes asymmetric Diels-Alder reactions, 1,3-dipolar additions and pyrrole alkylations in high enantiomeric excess.

Used in first highly enantioselective organocatalytic Diels-Alder reaction and 1,3-dipolar addition.

Rechtliche Hinweise

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

Sicherheitshinweise

• Lagerklassenschlüssel: 13 - Non Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)