547794

Tris-[N,N-bis-(trimethylsilyl)-amido]-neodym(III)

97%

• Synonym(e): 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine neodymium(III) salt
• Lineare Formel: Nd(N(Si(CH₃)₃)₂)₃
• CAS-Nummer: 148274-47-9
• Molekulargewicht: 625.39
• MDL-Nummer: MFCD03427089
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 24878980

Eigenschaften

• Assay: 97%
• Form: solid
• Eignung der Reaktion: reagent type: catalyst; core: neodymium
• mp (Schmelzpunkt): 156-159 °C (lit.)
• SMILES String: C[Si](C)(C)N([Nd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/3C6H18NSi2.Nd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
• InChIKey: LWKIKGQVWYVALF-UHFFFAOYSA-N

Beschreibung

Anwendung

Reagent for synthesis of:

• Imidophosphinate complexes of lanthanides
• Neodymium methoxides containing thienyl substituents
• Phenylene-bridged binuclear organolanthanide complexes
• Near-infrared photoluminescent neodymium(III) complexes

Reagent for:

• Rare-earth metal carboxylate-based catalysts
• Regioselective C-H activation

Sicherheitshinweise

• Piktogramme: GHS02,GHS05
• Signalwort: Danger
• H-Sätze: H228,H261,H314
• P-Sätze: P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): 36.0 °F - closed cup
• Flammpunkt (°C): 2.2 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges