516805

4,4′-Oxydianilin

97%

• Synonym(e): 4,4′-Diamino-diphenylether, Bis-(4-aminophenyl)-ether
• Lineare Formel: O(C₆H₄NH₂)₂
• CAS-Nummer: 101-80-4
• Molekulargewicht: 200.24
• Beilstein: 475735
• EG-Nummer: 202-977-0
• MDL-Nummer: MFCD00007863
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24873898
• NACRES: NA.22

Eigenschaften

• Dampfdruck: 10 mmHg ( 240 °C)
• Qualitätsniveau: 100
• Assay: 97%
• Form: solid
• mp (Schmelzpunkt): 188-192 °C (lit.)
• SMILES String: Nc1ccc(Oc2ccc(N)cc2)cc1
• InChI: 1S/C12H12N2O/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H,13-14H2
• InChIKey: HLBLWEWZXPIGSM-UHFFFAOYSA-N

Beschreibung

Anwendung

4,4′-Oxydianiline can be used as a reactant to synthesize:

• Aromatic polyamides by polycondensation with aromatic dicarboxylic acids.
• Azomethine bisphenols by reacting with aromatic aldehydes, which can be used to synthesize polyazomethines by the oxidative polycondensation in the presence of NaOCl as an oxidant.
• Polyguanamines by the chemoselective polycondensation with 2-amino-4,6-dichloro-1,3,5-triazine in the presence of potassium carbonate as a base.

It can also be used for the functionalization of carbon nanotubes, which can react with terminal dianhydrides to synthesize polyimide aerogels.

Sicherheitshinweise

• Piktogramme: GHS06,GHS08,GHS09
• Signalwort: Danger
• H-Sätze: H301 + H311 + H331,H317,H340,H350,H361fd,H373,H410
• P-Sätze: P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Gefahreneinstufungen: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 1 - Carc. 1B - Muta. 1B - Repr. 2 - Skin Sens. 1 - STOT RE 2 Oral
• Zielorgane: Thyroid
• Lagerklassenschlüssel: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flammpunkt (°F): 426.2 °F - closed cup
• Flammpunkt (°C): 219 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges