446939

N-(Triphenylphosphoranyliden)-1H-benzotriazol-1-methanamin

90%

• Synonym(e): 1-[[(Triphenylphosphoranylidene)amino]methyl]benzotriazole, Betmip
• Empirische Formel (Hill-System): C₂₅H₂₁N₄P
• CAS-Nummer: 124316-00-3
• Molekulargewicht: 408.43
• MDL-Nummer: MFCD00274644
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24868307
• NACRES: NA.22

Eigenschaften

• Assay: 90%
• Eignung der Reaktion: reaction type: C-C Bond Formation
• Verunreinigungen: 10% N-(triphenylphosphoranylidene)-2H-benzotriazole-2-methanamine
• mp (Schmelzpunkt): 116-122 °C (lit.)
• SMILES String: C(N=P(c1ccccc1)(c2ccccc2)c3ccccc3)n4nnc5ccccc45
• InChI: 1S/C25H21N4P/c1-4-12-21(13-5-1)30(22-14-6-2-7-15-22,23-16-8-3-9-17-23)26-20-29-25-19-11-10-18-24(25)27-28-29/h1-19H,20H2
• InChIKey: IOSUDUVEOWKKBL-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Grignard reaction
• Preparation of N,N-Bis(but-3-enyl)amines via aza-Wittig reaction with aldehydes, followed by a double Grignard reaction with allylmagnesium bromide
• Organic synthesis of N-alkyliminophosphoranes and a-functionalized N-alkyliminophosphoranes

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves