340529

(4S,5R)-(−)-4-Methyl-5-phenyl-2-oxazolidinon

99%

• Empirische Formel (Hill-System): C₁₀H₁₁NO₂
• CAS-Nummer: 16251-45-9
• Molekulargewicht: 177.20
• MDL-Nummer: MFCD00066226
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24860823
• NACRES: NA.22

Eigenschaften

• Assay: 99%
• Optische Aktivität: [α]25/D −168°, c = 2 in chloroform
• Optische Reinheit: ee: 99% (HPLC)
• mp (Schmelzpunkt): 121-123 °C (lit.)
• SMILES String: C[C@@H]1NC(=O)O[C@@H]1c2ccccc2
• InChI: 1S/C10H11NO2/c1-7-9(13-10(12)11-7)8-5-3-2-4-6-8/h2-7,9H,1H3,(H,11,12)/t7-,9-/m0/s1
• InChIKey: PPIBJOQGAJBQDF-CBAPKCEASA-N

Beschreibung

Anwendung

Versatile chiral auxiliary for asymmetric synthesis. For a review, see Aldrichimica Acta.

(4S,5R)-(-)-4-Methyl-5-phenyl-2-oxazolidinone may be used to synthesize (4S,5R)-N-tert-butyloxycarbonyl)-4-methyl-5-carboxy-2-oxazolidinone and (+)-pumiliotoxin B.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)